The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
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The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The quantity of salt to be added depends on the qualities desired in the
leather, and upon whether chloride or sulphate liquors are employed;
salt in chloride-liquors increasing the softness of the leather, but in
excess tending to flatness, while in sulphate-liquors it practically
diminishes their basicity by converting the chromium sulphate into the
equivalent chloride, which, as Eitner points out, behaves as a less
basic salt, and hence but little advantage is to be gained from its use.
It is best to begin with a very weak liquor, to avoid drawn grain, and
for the same purpose a preparatory tannage with alumina salts, or an
addition of alum or sulphate of alumina and salt may be made to the
first liquor, as the attraction of the chrome salt for the fibre is
sufficient to produce a chrome tannage, even in presence of excess of
alumina salts. 10 lb. of chrome alum will tan about 100 lb. of wet pelt,
but more must be used for the first parcel; as to avoid loss of time,
the skins may be tanned out in a pretty strong liquor. The bath has a
tendency to become acid by use, and before strengthening, it may be
necessary to add some more soda solution. Very little additional salt is
required, as it is only absorbed by the skins to a small extent,
probably as chromic chloride. As the liquors gradually become charged
with sulphates, it is best to work them out like bark liquors, and not
to go on strengthening the same liquor indefinitely. If old liquors are
used for green goods, it is not necessary to neutralise them with soda
before use, as Eitner has shown that less basic liquors colour more
evenly and with less tendency to produce drawn grain.
Basic chrome liquors, such as have been described, may also be used in
chrome combination tannage. It is generally best to let the light
vegetable tannage precede the chrome, and lightly tanned skins, such as
“Persians” and East India kips, acquire many of the qualities of
chrome-tanned leather by the treatment. The effect is still further
increased by a previous detannisation of the leather with alkaline
solutions (see p. 241). Several firms beside Dennis now supply basic
chrome liquors ready prepared for use.
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