The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Whether acid be used or not, the butts are now usually suspended in deep
pits containing old and nearly exhausted tan liquors. These liquors
contain a certain amount of lactic and acetic acids, derived by
fermentation from the sugary matters of the tanning materials, and also
in some cases, weak acids originally present in the materials
themselves. These acids are most important to successful tannage, and
their effect is twofold; in the first place, they neutralise and remove
any lime which still remains in the butts; and, secondly, they bring the
butt into a slightly acid condition, in which it remains plump and
swollen in the liquors, while the tannin gradually penetrates and tans
the fibre. If, as frequently happens, especially in modern yards where
extracts are very largely used, the natural acid of the liquors is not
sufficient for this purpose, the lime combines with the tanning matters,
and the butts either become discoloured at once, or darken by exposure
and oxidation, when they come to be dried, while the pelt remains flat
and insufficiently swollen. To avoid this trouble, resort is sometimes
had to artificial acidification of the liquors. As a general rule, it
may be stated that it does not answer to mix the stronger mineral acids
directly with the liquors, but lactic and acetic acids may be used, or
even oxalic acid may be added to the suspenders in such quantities as to
precipitate and remove the lime which they contain, setting free the
organic acids with which it had been combined. The use of oxalic acid
should never be pushed further than this, as it has a most powerful
swelling action on the hide; and goods which are too much swollen by
acids tan dark and brittle.
After the hides have remained from ten days to a fortnight in the
suspenders, they are usually laid in pits called “handlers” which are
worked in series of 6, 8, or 10 pits, containing the same number of
packs of goods. The weakest liquor from the youngest pack is run to the
suspenders daily, a new and stronger liquor is run to the pit, which now
becomes the head of the series, into which the oldest and most tanned
pack of butts is moved; and the next takes its place and liquor, and so
on down the series, the youngest pack finally occupying the place which
had previously been taken by the last but one. In this way each pack
receives a change of liquor of regularly graduated strength; and during
the time which it remains in the handlers, passes from a strength of
perhaps 20° Bkr. (sp. gr. 1·020) to one of about 40° Bkr. (sp. gr.
1·040). During this part of the process the butt is completely or nearly
coloured through, and is then ready for the “layers.”
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account