The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
If the proportion of free acid in the suspender liquors is as it ought
to be, it is probably rather advantageous than otherwise for a little
lime to remain in the interior of the hide, as it keeps the pelt in a
plump condition during the first stages of colouring, quickens the
penetration of the tannin, and lessens the tendency to “drawn” or
wrinkled grain, which arises when the goods go into the liquors in a
flat or fallen condition. The causes of drawn grain are often a little
obscure. Of course that case needs no elucidation in which the hides are
submitted to the tanning liquor in a creased or wrinkled condition,
which is simply fixed and made permanent. This may arise, either from
carelessness in handling the goods before taking into the suspenders, or
from the way in which they are slung to the sticks, which often draws
them into long wrinkles, afterwards difficult to remove. Drawn grain in
general, however, arises from the grain-surface becoming tanned and
fixed in area, while the substance of the hide is in a more extended
condition than that which it assumes as tannage proceeds. Hides in a
flat and unswollen condition are thinner, the fibres are slenderer and
looser than when swollen, and consequently the hide has a larger area.
If, after the grain is tanned, the substance of the hide becomes
contracted in the liquor, either by swelling with acids, or by the
direct action of the tannin on the interior fibres, the grain is certain
to be shrivelled, like the skin of a dried apple. A similar effect,
produced in a mechanical way, may always be noted where a hide has been
coloured hanging grain-side out over a pole, so that the surface is
extended at the bend, on which long wrinkles are formed as soon as it is
straightened.
A hide in a slightly alkaline condition colours, and even tans more
quickly than one which is acid. In presence of a trace of lime, and
deficiency of free acid in the suspender liquor, tannages of valonia and
bark give the butt a sort of lemon-yellow colour, which is not in itself
injurious, and which disappears as the hides advance into more acid
liquors, but which is a sign of danger, as showing that no excess of
acid exists in the suspender-liquors. Gambier gives pelt perfectly free
from lime a pale buff colour, but where lime is present, the colour is
always reddish, and much darker, and this coloration does not disappear
so readily as that with valonia, so that if gambier is to be used in the
first liquors, care should be taken to remove all lime from the surface.
The only known tannin which gives no insoluble compound with lime is
that of the babool pod (sometimes called “gambia-pod”), which is
frequently used in India as a bate, and which would probably prove very
useful in colouring liquors (pp. 165, 288).
Public-domain text, read in full here on John Shaqi.
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