The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
_Rumex hymenosepalum_, Canaigre, Gonagra (Cana agria), Red Dock, wild
pie-plant (Fig. 52). Common in sandy alluvial plains of Mexico and
Texas, and considerably resembling rhubarb. Its tuberous roots resemble
those of the dahlia, and contain, when air-dried, 25-30 per cent. of a
catechol tannin, probably allied to that of mimosa. Undried, the roots
contain about 68 per cent. of water and only 8 per cent. of tannin. When
well harvested by slicing thin and rapidly drying, it gives leather a
bright orange colour, and, it is said, considerable weight and firmness,
and is thus specially suitable for use in retanning and finishing light
goods and harness leather. Besides tannin, the root contains a yellow
colouring matter, and about 8 per cent. of starch, of which the granules
are very variable in form and size, but mostly oval or elongated. They
do not stain readily with iodine till they have been well washed, or
treated with dilute sulphuric acid. Both the starch and tannin are
contained in large and somewhat thin-walled cells, and the sliced
material is easily extracted at low temperatures. Greater heat
gelatinises the starch, and extracts a darker colour. The best
temperature for extraction is between 30° and 50° C. (see p. 348).
[Illustration: FIG. 52.--Canaigre (_Rumex hymenosepalum_). ‘New
Commercial Drugs and Plants,’ T. Christy.]
The root is most readily grown from tubers or portions including the
crown, as the plant seeds sparingly. Sandy soils, subject to inundation
or irrigation, seem best suited to its culture. In California and
Arizona the growth begins in October or November with the winter rains,
blooming about the end of January, while the leaves die down in May and
the roots remain dormant during the summer. It is not important at what
time the roots are harvested, and they seem to improve in percentage of
tannin up to the second year, after which they become darker and
deteriorate.
The harvested crop should be sliced into thin pieces and rapidly dried
at a low temperature, or still better, converted at once into extract.
This is already done on a considerable scale at Deming, New Mexico. The
residue after extraction is used in America as cattle-food; and might no
doubt be also applied to the production of alcohol.
Planting takes place in autumn, in rows, say 30 inches apart, with 10
inches between each root. Roots for “seed” should be kept in the ground
or stored in dry sand. This should yield a crop of 10 tons per acre in
an average season.
_References._--Report U.S. Commissioner of Agriculture, 1878, pp. 119
_et seq._; Trimble, Am. Jour. of Pharmacy, p. 395, 1889; Canaigre, Bull.
No. 7, Arizona Agr. Expt. Station, 1893; ‘Canaigre or Tanner’s Dock,’
Bull. No. 105, University of California, Berkeley, Cal.; ‘Canaigre
Tannin,’ Trimble and Peacock, Philadelphia, 1893; ‘Report to the German
Leather Trades Association,’ by V. Schroeder, 1894; ‘Il Canaigre,’ E.
Andrieis, Turin, 1899.
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