The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
_Loxopteryngium Lorenzii._ Span. _Quebracho colorado._ South America,
especially Argentine Republic; the highest proportion of tannin
occurring in the wood from Gran Chaco district. Wood contains on an
average about 20 per cent. of a red, difficultly-soluble tannin,
yielding “reds,” and containing catechol and phloroglucol. The tannin is
not very soluble in water, and hence can only be used in weak liquors,
but is very astringent, and gives a firm, reddish leather. The wood also
contains a catechin[139] and a colouring matter, fustin, identical with
that of “young fustic.” It is imported into England, and more largely to
Havre and Hamburg, in logs, which are there chipped like logwood, and
either used direct for tanning, or made into extract. A very cheap tan.
With alum it gives a yellow colour. The extract usually dissolves to a
fawn-coloured turbid solution. Many quebracho extracts are now made
completely soluble by treatment with alkalies or sulphites (cp. p. 338).
[139] See P. Arata, Journ. Chem. Soc., 1878, A, p. 986; 1881, A, p.
1152; and Perkin and Gunnell, Trans. Chem. Soc., 1896, 1303.
“Quebracho” means “axebreaker,” and is consequently applied to a variety
of hard woods. Its specific gravity is 1·27-1·38, and it therefore sinks
in water.
_Pistacia lentiscus_, Ital. _Pistacio_, Fr. _Lentisque_. Sicily,
Cyprus, Algeria. Small myrtle-like leaves contain from 12-19 per cent.
of a catechol-tannin, and are very largely used in the adulteration of
sumach. Leather tanned with sumach adulterated with this material
darkens and reddens on exposure to light and air, and for this reason
its use in many cases is decidedly injurious. In Cyprus and the East it
is known as “_Skens_,” Ital. _Schinia_, Fr. _Poudre de Lentisque_, in
England, often called Cyprus sumach. (Cp. p. 272.)
_P. orientalis_, _terebinthus_, _vera_, etc., India, Mediterranean.
Various aphis galls, 30-40 per cent. tannin. A sample of galls of
_Pistacia vera_, “_Gool-i-pista_,” India, recently examined in the
Author’s laboratory, contained 30 per cent. of a light-coloured tannin.
_Schinus molle_, “Molle,” Buenos Ayres. Leaves only used; said to
contain 19 per cent. tannin.
_S. Aroeira_, Brazil. Said to contain 14 per cent. tannin.
_Rhus coriaria_, Sicilian sumach. Ital. _Somacco_. (Fig. 53.) A shrubby
bush, of which leaves and small twigs are used.
[Illustration: FIG. 53.--Sicilian Sumach (_Rhus coriaria_).]
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