The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
into the eye of the leach (which is preferably central) so that the
heated water flows over its top, and percolates downwards through the
material to be washed. Two forms of these boiling and mixing jets made
by Messrs. Körting are shown in Figs. 80 and 81.
[Illustration: FIGS. 80 and 81.--Boiling and Mixing Jets.]
Batteries of closed copper extractors, worked on the press system, and
similar to those used in extracting sugar from beetroot, have frequently
been advocated, but are very costly, and have no other advantage over
open vats than that the liquor can be forced through the series by
pressure, instead of circulating by gravity. No advantage is gained by
boiling under pressure, since even boiling in open vats has been shown
to destroy tannin, darken the colour of the liquor, and increase the
amount of insolubles, and higher temperatures are still more injurious.
Heating the weakest leach in the press-leach system promotes the even
circulation of the liquor, since the warm weak liquor is much lighter
than the colder and stronger liquors in the forward leaches, and so
floats on the top, and presses the stronger liquor uniformly downwards.
It also has the advantage that the liquors are cooled before they are
strong enough for the yard, while in tanneries where all the leaches are
heated, expensive tubular coolers are often employed. As the liquor
cools, much of the colouring matters and reds dissolved in the hot
liquor separate, and are filtered out by the tanning material, so that
much brighter and lighter coloured liquors are obtained.
[Illustration: FIG. 82.--Sprinkler-Leach.]
_Sprinkler-Leaches_, Fig. 82, were formerly used in many tanneries and
extract factories, especially in the United States. They were introduced
by Allen and Warren, and yield a liquor which is at first very strong,
but which becomes very rapidly weaker as the running is continued. These
leaches are similar in principle to the mashing-tub and sparger of the
brewer, but the process is not well adapted for tanners’ use, as the
material is left too much exposed to the air, which is apt to cause
oxidation and loss of tannin. It is also extremely difficult to
completely exhaust the material without using an impracticably large
volume of water. Sprinkler-leaches are arranged so as to spray the
liquor, or water, on to the top of the solid material which is to be
extracted at such a rate that it flows out just as rapidly as it flows
into the vat. Some idea of the great amount of oxidation and consequent
loss of tannin which takes place in this form of extractor may be
obtained when it is remembered that this same method is now used for the
destruction of sewage matter by spraying it on to beds of coke so that
it may be mixed with as much air as possible before it is attacked by
the bacteria of the coke-beds (see p. 473), and also to oxidise weak
alcohol to acetic acid in the “quick vinegar process.”
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