The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The use of ferrocyanides has been suggested as a means of precipitating
iron and copper present in extracts, and it may also be pointed out,
that with many red-coloured tanning materials, such as hemlock and
quebracho, the addition of small quantities of alum to the tanning
liquor effects considerable improvement in colour, not only by
precipitating a part of the difficultly soluble “reds,” but by
developing the yellow colour of certain colouring matters (quercetin,
myricetin, etc.) which may be present. Such an addition does no harm in
the case of soft leathers, but would probably be injurious in a
sole-leather tannage.
The liquors, whether direct from the leaches or from the decolorising
vats, must next be concentrated by evaporation (Chap. XXVI.), to sirupy
consistency for liquid extracts, or until they will become nearly solid
on cooling, if a solid extract is required. As has already been stated,
the action of heat tends to cause a loss of tannin and a darkening of
colour by decomposition and the formation of insoluble reds. To reduce
this loss to a minimum, the weak liquors are evaporated with as little
access of air and at as low a temperature as possible, and these
conditions are best obtained by the use of steam-heated vacuum pans.
[Illustration: FIG. 83.--Triple-effect Yaryan Evaporator.]
For concentration to gravities not exceeding 1·200, the Yaryan apparatus
made by Mirrlees, Watson and Yaryan, of Glasgow, is that most employed.
The general arrangement of a “triple effect” machine of this make is
shown in Fig. 83, and the internal construction in Fig. 84. Each body
consists of a strong casing into which steam is admitted, and which is
traversed by copper tubes which terminate in a separating chamber at the
further end, which is maintained at a low pressure by an air-pump. The
liquid to be evaporated is admitted into the tubes, and is immediately
converted into spray by the steam generated from it, and swept forward
into the separating chamber, from which it is withdrawn by a pump. The
steam before going to the air-pump (or, in the case of “multiple
effects,” to the next body), is passed through a “catch-all,” to
separate any spray still retained in the steam. Thus the liquor to be
evaporated will pass through the entire apparatus in four or five
minutes, and may be concentrated from a gravity of 1·02 or 1·03 to that
of 1·20 without ever having been heated above 70° C. (160° F.). Unless
fuel is very cheap, which is often the case where the spent tanning
material can be used to raise steam, it is advisable to use a double or
triple effect, in which the steam from the evaporation of the weakest
liquor in the first body is used to heat the second, which is maintained
at a lower vacuum, and so on. In this way the steam is made to do nearly
double or triple duty. As the steam from the extract-liquors contains
acids which corrode iron, it is necessary to have the casing as well as
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