The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
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The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
If the hydrochloric acid were just sufficient to combine with the
whole of the sodium, we should have an equilibrium containing much
(ionised) sodium chloride and little sodium acetate, together with much
free acetic acid, and little hydrochloric. Thus the “strong” acid would
displace the weak one.
Taking another example, we add sodium acetate to a solution of acetic
acid. As the ionisation-pressure of the acetic acid is much less than
that of sodium acetate, and both have a common acet-ion, the ionisation
of the acetic acid will diminish, and more undissociated acetic acid
will form, till by its concentration the two pressures are equalised.
The total quantity of free acetic acid will be unchanged, but a less
proportion of it will be ionised, and it will act like a weaker acid.
This reduction of the activity of a weak acid by the addition of its
neutral salt is often made use of by chemists. Instances in tanning
practice are the use of excess of potassium dichromate with chromic acid
in the chrome tanning process, the effect of neutral salts in
“mellowing” the action of tanning liquors, and the use of salt in
“pickling.”
Let us now try to apply these facts to the physics of tanning, taking
first the simplest cases, where electrolytic dissociation does not take
place. We may consider the wet hide as made up of a mass of fibres of
gelatine-jelly, with interspaces which are filled with water. In fact,
for many purposes of experiment we may substitute for hide, mere sheets
of swollen gelatine, so as to avoid the complications introduced by the
water or solution mechanically retained between the fibres.
If we place a sheet of dry gelatine in water, it swells, absorbing
perhaps seven or eight times its weight of water, but does not
appreciably dissolve. A condition of equilibrium is reached when the
attraction of the water-molecules for the gelatine is equal to the sum
of the cohesive attraction of the gelatine for itself and the internal
attraction of the water outside. An increase of the cohesion of the
gelatine would tend to make it contract and expel part of the water, and
this contraction would tend further to increase both the cohesion of the
gelatine, and its attraction on the diminished number of water molecules
it contained, and clearly these causes would act in opposing directions.
The equilibrium is therefore a very unstable one, and slight causes
might be expected to produce great changes in the degree of swelling,
which is indeed the case. If we increase the temperature we diminish the
cohesion of the gelatine, till at a point it becomes less than its
attraction for the water, and the jelly suddenly loses its solid
condition and dissolves.
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