The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
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The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The effect of acids and alkalies has been studied by Procter and others
on actual pelt as well as on gelatine, and has been found to be
qualitatively, if not quantitatively quite similar to that on gelatine,
though from the acid retained mechanically in the interfibrous spaces,
exact quantitative determination is more difficult. The amount of
swelling produced is not proportional to the strength of the acid, some
weak and little ionised acids such as lactic producing larger swelling
than stronger acids such as hydrochloric and sulphuric, of which the
ionic pressure in the external solution is greater. Dilute solutions
generally produce greater swelling than more concentrated, so that where
swelling is required without destructive effect on the fibre, dilute
solutions of such weak acids are to be preferred, and the presence of
neutral salts is to be avoided. On the other hand, where it is desired
to remove lime, or to bring the pelt into an acid condition without
swelling, the addition of neutral salts, and especially of chlorides is
advantageous. A very important application of this principle is the
“pickling” of sheep-skins, and especially of sheep-grains, in order to
preserve them for export. The principle of this operation is that the
skins are first swollen slightly with sulphuric acid, and the swelling
is then reduced by salt, either added, or used in a subsequent bath. In
practice, salt is now generally also added to the first bath to moderate
the swelling. A suitable strength for the “rising solution” is about 80
grm. common salt, and 7·5 grm. sulphuric acid per litre. 100 c.c. of
this solution will therefore require about 15 c.c. of N/1 alkali to
neutralise it, and it should be tested after each lot of skins, and
maintained at the same strength by suitable additions of acid. The acid
absorbed by the skins is mainly hydrochloric, sodium sulphate
accumulating in the bath. The salt is not absorbed by the skins in the
same way as the acid, but will be continually diluted by the water they
bring in, and occasional additions of salt must therefore be made, the
density being maintained at about 65° Bkr. (1·065 sp. gr.) After
paddling or being stirred in this bath for about ¹⁄₂ or ³⁄₄ hour the
skins are transferred to saturated brine, and stirred in it till fully
fallen in thickness, the density of the liquid being maintained by
excess of salt. They may be allowed to remain some hours in the
saturated brine with advantage.
Public-domain text, read in full here on John Shaqi.
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