The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
_Dry and dry-salted hides_ require much longer soaking than wet-salted,
the amount naturally depending on the thickness of the hide and the
character of drying. Even thin skins when strongly dried require
considerable time to soften and swell the fibres, although they soon
become wet-through and flexible. Many different methods of soaking have
been employed. Sometimes hides are suspended in running water; sometimes
laid in soaks which may be either renewed, or allowed to putrefy;
sometimes in water to which salt, borax or carbolic acid has been
added, to prevent putrefaction; and more recently weak solutions of
caustic soda, sulphide of sodium or sulphurous acid have been used with
much success.
[Illustration: FIG. 21.--American Wash-wheel.]
The first of these methods, were it desirable, is rarely possible in
these days of River Pollution Acts; of the others, it is difficult to
say which is better, since the treatment desirable varies with the
hardness of the hide and the temperature at which it has been dried. The
great object is to thoroughly soften the hide without allowing
putrefaction to injure it. As dried hides are often damaged already from
this cause, either before drying, or from becoming moist and heated on
shipboard, it is frequently no easy matter to accomplish this. The fresh
hide, as has been seen, contains considerable portions of albumin, and
if the hide is dried at a high temperature, this may become wholly or
partially coagulated and insoluble. The gelatinous fibre and the coriin
(if indeed the latter exists ready formed in the fresh hide) do not
coagulate by heat, but also become less readily soluble. Gelatin dried
at 130° C. can only be redissolved by acids, or water at 120° C.
Eitner[68] experimented with pieces of green calf-skin of equal
thickness, which were dried at different temperatures, with results
given in the following table:--
-------+-----------+---------+---------+-------------+--------------
Sample.|Temperature|Remarks. |Time of | Remarks. | Coriin
|of Drying. | |Softening| |Dissolved by
| | |in Water.| |Salt Solution.
-------+-----------+---------+---------+-------------+--------------
I. | 15° C. |In vacuo |24 hours |{Without } |1·68 per cent.
| | |{mechanical} |
II. | 22° C. |In sun |2 days |{ work } |1·62 „
| | | | |
III. | 35° C. |In drying|5 „ |Twice worked |0·15 „
| | closet | | |
| | | | |
| | | {Refused to soften} |
IV. | 60° C. | „ | {sufficiently for } |traces
| | | {tanning } |
-------+-----------+---------+---------+-------------+--------------
[68] Gerber, 1880, p. 112.
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