The Progress of Invention in the Nineteenth Century.Byrn, Edward W. (Edward Wright)
History
The Progress of Invention in the Nineteenth Century.
Byrn, Edward W. (Edward Wright)
Inventions -- History; Inventions -- History -- 19th century
In 1802 Dr. Wollaston, in repeating Newton’s experiments, admitted the
beam of light through a very narrow slit, instead of a round hole, and
noticed that the spectrum, as spread out in its colors, was not a
continuous shading from one color into another, but he found black lines
crossing the spectrum. These black lines were, in 1814, carefully mapped
by a German optician, named Fraunhofer, and were found by him to be 576
in number. The next step toward the spectroscope was made by Simms, an
optician, in 1830, who placed a lens in front of the prism so that the
slit was in the focus of the lens, and the light passing through the
slit first passed through the lens, and then through the prism. This
lens was called the “Collimating” lens. With these preliminary steps of
development, Prof. Kirchhoff began in 1859 his great work of mapping the
solar spectrum, and he, in connection with Prof. Bunsen, found several
thousand of the dark lines in the spectrum, and laid the foundation of
_spectrum-analysis_, or the determination of the nature of substances
from the spectra cast by them when in an incandescent state.
[Illustration: FIG. 199.--KIRCHHOFF’S FOUR-PRISM SPECTROSCOPE.]
The form of Kirchhoff’s spectroscope is given in Fig. 199. The slit
forming slide is seen on the far end of the tube A, and is shown in
enlarged detached view on the right. The collimating lens is contained
in the tube A. The beam of light entering the slit at the far end of the
tube A, passes through the lens in that tube, and then passes
successively through the four triangular prisms on the table, and is
successively bent by these and thrown in the form of a spectrum into the
telescopic tube B, and is seen by the eye at the remote end of said
tube B. The greater the number of prisms the wider is the dispersion of
the rays and the longer is the spectrum, and the more easily studied are
the peculiar lines which Wollaston and Fraunhofer found crossing it. It
was the presence of these black lines on the spectrum which led to the
development of the spectroscope and established its significance and
value. The work which the spectroscope does is simply to form an
extended spectrum, but this spectrum varies with the different kinds of
light admitted through the slit, the different kinds of light showing
different arrangement of colored bands and dark lines, and such a
definite relation between the light of various incandescing elementary
bodies and their spectra has been found to exist, that the casting of a
definite spectrum from the sun or stars indicates with certainty the
presence in the sun or stars of the incandescing element which produces
that spectrum. This application of the spectroscope is called
_spectrum-analysis_, and by rendering any substance incandescent in the
flame of a Bunsen burner, and directing the light of its incandescence
through the spectroscope, its spectrum gives the basis of intelligent
chemical identification. So delicate is its test that it has been
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