The Progress of Invention in the Nineteenth Century.Byrn, Edward W. (Edward Wright)
History
The Progress of Invention in the Nineteenth Century.
Byrn, Edward W. (Edward Wright)
Inventions -- History; Inventions -- History -- 19th century
_Metallurgy of Rarer Metals._--Although less in evidence than iron, this
has engaged the attention of the scientist from the earliest years of
the century. The full list of metals discovered since 1800 may be found
under “Chemistry.” The more important only are here given. Palladium and
rhodium were reduced by Wollaston in 1804. Potassium and sodium were
first separated in metallic form by Sir Humphrey Davy in 1807, through
the agency of the voltaic arc; barium, strontium, calcium and boron by
the same scientist in 1808; iodine by Courtois in 1811; selenium by
Berzelius in 1817; cadmium by Stromeyer in 1817; silicon by Berzelius in
1823, and bromium by Balard in 1826. Magnesium was first prepared by
Bussey in 1829. Aluminum was first separated in 1828 by Wohler, by
decomposing the chloride by means of potassium. Oersted, in 1827,
preceded him with important preliminary steps, and Deville, in 1854,
followed in the first commercial applications. In late years the
metallurgy of aluminum has made great advances. The Cowles process heats
to incandescence by the electric current a mixture of alumina, carbon
and copper, the reduced aluminum alloying with the copper. This process
is covered by United States patents to Cowles and Cowles, No. 319,795,
June 9. 1885, and Nos. 324,658 and 324,659, August 18, 1885. It has,
however, for the most parts been superseded by the process patented by
Hall, April 2, 1889, No. 400,766, in which alumina dissolved in fused
cryolite is electrically decomposed.
In the metallurgy of the precious metals probably the most important
step has been the _cyanide process_ of obtaining gold and silver. In
1806 it was known that gold was soluble in a solution of cyanide of
potassium. In 1844 L. Elsner published investigations along this line,
and demonstrated that the solution took place only in the presence of
oxygen. McArthur and Forrest perfected the process for commercial
application, and it is now extensively used in the Transvaal and
elsewhere. It is covered by their British patent, No. 14,174, of 1887,
and United States patents No. 403,202, May 14, 1889, and No. 418,137,
December 24, 1889, which describe the application of dilute solutions of
cyanide of potassium, not exceeding 8 parts cyanogen to 1,000 parts of
water: the use of zinc in a fine state of division to precipitate the
gold out of solution, and the preparatory treatment of the partially
oxidized ores with an alkali or salts of an alkali. By this
solution-process gold, in the finest state of subdivision, which could
not be extracted by other processes from the earthy matters, may be
recovered and saved in a simple, practical and cheap way.
[Illustration: FIG. 263.--EDISON MAGNETIC CONCENTRATING WORKS. THE GIANT
CRUSHING ROLLS.]
[Illustration: FIG. 264.--EDISON MAGNETIC CONCENTRATOR.]
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