History, Modern -- 19th century; Nineteenth century
it has been applied by him and by Newcomb, not only for the better
determination of the velocity of light in air, but for the solution
of many other related problems of first importance. Michelson’s final
determination of the absolute velocity of light (in the ether) is
everywhere accepted as authoritative.
Another discovery in optics entirely accomplished during the nineteenth
century and of the very first importance is generally known as
“Spectrum Analysis.” This discovery has not yet ceased to excite
admiration and even amazement, and especially among those who best
understand it. By its use hitherto unknown substances have become
known; to the physicist it is an instrument of research of the greatest
power, and perhaps more than anything else it promises to throw light
on the ultimate nature of matter; to the astronomer it has revealed
the composition, physical condition, and even the motions of the most
distant heavenly bodies, all of which the philosophy of a hundred years
ago would have pronounced absolutely impossible.
The beginning of spectrum analysis was in 1802, when an Englishman, Dr.
Wollaston, observed dark lines interrupting the solar spectrum when
produced by a good prism upon which the sunlight fell after passing
through a narrow slit. About ten years later, Fraunhofer, at Munich, a
skilful worker in glass and a keen observer, discovered in the spectrum
of light from a lamp two yellow bands, now known as the sodium, or
“D” lines. Combining the three essential elements of the modern
spectroscope, the slit, the prism, and the observing telescope, he saw
in the spectrum of sunlight “an almost countless number of dark lines.”
He was the first to use a grating for the production of the spectrum,
using at first fine wire gratings and afterwards ruling fine lines
upon glass, and with these he made the first accurate measures of the
length of light waves. He did not, however, comprehend the full import
of the problem which he thus brought to the attention of physicists.
About twenty years later Sir John Herschell studied the bright line
spectra of different substances and found that they might be used to
detect the presence of minute quantities of a substance whose spectrum
was known. Wheatstone studied the spectrum of the electric arc passing
between metals, and in 1874 Dr. J. W. Draper published a very important
paper on the spectra of solids with increasing temperature. Although
quite in the dark as to the real nature of the phenomena with which
they were dealing, these observers paved the way for the splendid work
of the two Germans, Kirchoff and Bunsen, who, about 1860, found the key
to this wonderful problem and made the science of spectrum analysis
substantially what it is to-day. Its fundamental principles may be
considered as few and comparatively simple.
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