History, Modern -- 19th century; Nineteenth century
Many important contributions to the theory and practice of spectrum
analysis have been made since the time of Kirchoff and Bunsen, only
two or three of which can be referred to here. Instrumental methods by
which spectra are produced and examined have been greatly perfected,
and this is especially true of what is known as the “diffraction
grating” first used by Fraunhofer. A quarter of a century ago
Rutherford, of New York, constructed a ruling engine by means of which
gratings on glass and spectrum metal were ruled with a precision
greatly exceeding what had before been possible. A few years later
Rowland, of Baltimore, made a notable advance in the construction of
a screw far more perfect than any before made, producing gratings of
a fineness and regularity of spacing far ahead of any others, and
especially by the capital discovery of the concave grating, by means
of which the most beautiful results have been obtained. Very recently
Michelson, of Chicago, has invented the echelon spectroscope, which,
although greatly restricted in range, exceeds all others in power of
analysis of spectral lines. In his hands this instrument has been most
effective in the study of the influence of a strong magnetic field
upon the character of the spectrum from light produced therein, a most
interesting phenomenon first observed by Zeeman and one which promises
to reveal much concerning the relation of molecular activity to light
and to magnetic force.
The development of spectrum analysis was necessarily accompanied by a
recognition of the identity of radiant heat and light. The study of
radiant heat, which was carried on during the earlier years of the
century by Leslie, and later by Melloni and Tyndall, by what might be
called thermal methods, has been industriously pursued during the last
two decades by processes similar to those adopted for visual radiation.
The most notable contribution to this work is the invention of the
_bolometer_, by Langley, who, at Allegheny, and later at Washington,
has made exhaustive studies of solar radiation in invisible regions
of the spectrum, especially among the waves of greater length than
those of red light, where he has found absorption lines and bands
similar in character to those observed in the visible spectrum. He has
also studied the absorption of the earth’s atmosphere, the relation
of energy to visual effect, and many other interesting problems, the
solution of which was made possible by the use of the bolometer.
Mention must also be made of the invention by Michelson of an
interference comparator, by means of which linear measurements by
optical methods can be accomplished with a degree of accuracy hitherto
unheard of. With this instrument Michelson has determined the length of
the international prototype metre in terms of the wave length of the
light of a particular spectral line, thus furnishing for the first time
a satisfactory _natural_ unit of length.
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