The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
1. _On the Specific Heat of Gases, by_ MM. de la Rive _and_
Marcet.—The principle on which these philosophers proceeded in
their researches, was, to expose equal volumes of different gases
to an equal source of heat during equal times, and to judge, by the
augmentation of elastic force in each gas, the temperature which it
had acquired. The apparatus was a kind of manometer, and consisted
of a glass balloon to retain the gas, and a bent tube attached to
it, which, descending into a vessel of mercury, served to show, by
the column of metal within it, what was the elasticity of the gas.
This method was adopted, because, i. The gas was not altered in
volume by the change of temperature, its elasticity only changing:
ii. The temperature was indicated by the gas itself, and not by a
thermometer: iii. Water was easily separated previously from the
gases, and excluded from the apparatus: iv. All the gases were placed
in exactly the same circumstances, so as to render it unnecessary to
refer to any calculation for the purpose of comparison.
Two methods of applying heat were resorted to: in one the balloon,
containing the gas at a certain temperature, was placed in water at
a higher but constant degree, for a certain time (generally 4′),
and the elevation of temperature noticed: in the other, the balloon
with the gas was inclosed in a larger copper balloon, blackened
inside, and the space between the two exhausted as much as possible
of air; the apparatus being then immersed in warm water, the heat
gained access slowly to the gas, and the time of each experiment
was increased, at the same time that certain sources of error were
avoided.
The gases experimented with were, atmospheric air, oxygen, azote,
hydrogen, carbonic acid, olefiant gas, oxide of carbon, nitrous
oxide, nitrous gas, sulphuretted hydrogen, ammonia, sulphurous
acid, muriatic acid, and cyanogen. Great care was taken in their
preparation. The result of the experiment was very unexpected; for,
during the five minutes allotted for each, all had acquired the same
temperature,—a circumstance which proves that they all have the
_same specific heat_. The equal volumes of gas at the pressure of
65 centimeters (15.59 inches) and the temperature of 20°C., being
exposed to a source of heat at 30° C., acquired a mean temperature
of 6.32 degrees in five minutes, the extreme difference, in any of
the experiments, not being more than 0.04 of a [p201] degree. One gas
only forms an exception to the above statement, namely, hydrogen,
which was always heated more than the others, namely, to 6.6 degrees
in the five minutes. This effect is considered as due not to any
difference in specific heat, but to a difference in conducting power.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account