The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
Mere continuance of the heat had no effect in increasing the
precipitate either of this salt, or from aqueous solution of lime,
provided no part of the solution was at any time converted into
vapour; but if the solution only occupied a small part of the vessel,
and ebullition came on, then, although all the water might be
returned to the solution, yet the precipitation went on, and might
be [p203] increased _ad libitum_, particularly in the case of lime
water. The cause of the precipitate appears to be the same in all
these cases. The moment a drop of the solution is converted into
vapour, it deposits the quantity of lime or salt which it held in
solution; and in the case of bodies which dissolve so sparingly and
with so much difficulty, although the water be returned again to the
solution, it is incapable of re-dissolving what it has deposited. We
know that it would be a hopeless task to form a saturated solution of
lime by agitating with the water no more than the few grains which
it is capable of dissolving; and in the case of ebullition, when the
lime is once deposited, there should be the same difficulty in taking
it up.
Mr. Graham states that he has observed this effect not only in
lime-water and in solution of phosphate of magnesia, but to a certain
extent in all bodies of difficult solubility, in the sulphate of
lime, for instance, even when greatly diluted; and he believes that
the deposite from slight boiling observed in many mineral waters,
and generally attributed to the dissipation of carbonic acid gas,
depends, in some instances, upon this cause. However weak the
solution may be, it is evident that a portion of the salt may be
deposited in this way.
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