The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
And the manganesate of potash of Or being calcined
Potash 25.63 32.75
Manganese acid 52.44 67.25
Water 21.93 ------
------ 100.00
100.00
_Ann. des Mines_, 1827, p. 145.
10. _Heavy Muriatic Ether, and Hydrocarburet of Chlorine or Chloric
Ether_.—Some comparative experiments have been made on these two
substances by M. Vogel. He prepared the former of them by passing
chlorine gas into alcohol. The muriatic acid was then separated by
distilling the fluid from off chalk, in which operation the muriatic
ether and alcohol passed over together, and these were divided by the
addition of water, which dissolved the latter, and left the former.
The chloric ether was made as usual from chlorine and olefiant
gases. The results that were obtained by acting on these substances
by a high temperature, potash, phosphorus, &c., induced M. Vogel
to consider them as identical in composition, notwithstanding some
differences in their physical properties; the specific gravity of the
muriatic ether was 1.134, that of the chloric ether 1.214, and the
odour of the latter is more aromatic, and the taste more sweet than
of the former.
Whilst passing the chlorine into the alcohol, M. Vogel observed
[p205] that if the sun shone upon the substances when the action was
nearly complete, each bubble of chlorine as it entered the alcohol
produced a bright purple flame, a dense white vapour, and caused
violent concussions in the liquid; another curious instance, in
addition to the many that are known, of the power of solar light over
chemical action.—_Journ. de Pharm._ 1826, p. 627.
11. _Test for the Presence of Nitric Acid_.—The following method is
one devised by Dr. Liebig, for the detection of this substance, which
it will effect, he says, when there is not more than a four-hundredth
part of the acid present. The liquid to be examined must be mixed
with sufficient sulphuric solution of indigo to acquire a distinct
blue colour, a few drops of sulphuric acid added, and the whole
boiled. If the liquid contains a nitrate, it will be bleached, or,
if the quantity is very small, rendered yellow. By adding a little
muriate of soda to the liquid before applying heat, a five-hundredth
of nitric acid may easily be discovered.—_Ann. de Chimie_, xxxv. 80.
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