The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
26. _Fallacy of Infusion of Litmus as a Test_, _by_ M. Magnus.—When
pure water is heated for a sufficient time with infusion of litmus,
reddened by an acid, it restores the blue colour. It is supposed
that the heat gradually causes the free sulphuric acid, which had
occasioned the reddening, to combine with the excess of alkali
contained in the infusion, and thus to cause the restoration of the
blue colour. Hence this preparation cannot be used to test the [p215]
presence of ammonia in a solution, as water alone produces the effect
anticipated from the alkali. The earthy salts contained in ordinary
water also produce this effect.—_Jour. de Pharmacie_.
27. _Tests for the Natural Colouring Matter of Wine_.—M. A. Chevalier
states,—i. That potash may be employed as a re-agent, to ascertain
the natural colour of wines, which it changes from red to a bottle
green, or brownish green—ii. That the change of colour produced by
this substance upon wine is different for wine of different ages—iii.
That no precipitation of the colouring matter takes place, the latter
remaining dissolved by the potash—iv. That the acetate of lead should
not be employed as a test of the colour of wines, because it is
capable of producing various colours with wines of a natural colour
only—v. That the same is the case with lime-water, with muriate of
tin mixed with ammonia, and with subacetate of lead—vi. That ammonia
may be employed for this purpose, the changes of colour which it
produces not perceptibly varying—vii. That the same is the case with
a solution of alum to which a certain quantity of potash has been
added, and which may, therefore, be used for the purpose.—_Annales de
l’Industrie_.
28. _Test of the Presence of Opium_.—Dr. Hare says he can detect
opium in solution, when the quantity is not more than that given, by
adding ten drops of laudanum to half a gallon of water. The following
is the process:—a few drops of solution of acetate of lead is to
be added to the solution containing the drug; after some time an
observable quantity of meconiate of lead will fall down: from six to
twelve hours may sometimes be required, and the precipitation is best
effected in a conical glass vessel, for then, by gentle stirring now
and then to liberate that which adheres to the side, the insoluble
salt may be collected together at the bottom. About thirty drops of
sulphuric acid are then to be poured on to the meconiate by means
of a glass tube, after which as much of a solution of red sulphate
of iron is to be added in the same manner. The sulphuric acid will
liberate the meconic acid, and thus enable it to produce with the
iron the appropriate colour, which demonstrates the presence of that
acid, and consequently of opium.—_Silliman’s Journal_, xii. 290.
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