The Quarterly Journal of Science, Literature and the Arts, July-December, 1827Various
Science
The Quarterly Journal of Science, Literature and the Arts, July-December, 1827
Various
Arts -- Periodicals; Science -- Periodicals; Technology -- Periodicals
A given quantity of this indigogene was acted upon by ammonia, and
the weight of the undissolved blue portion ascertained, it appeared
that the weight of the pure portion dissolved was 0.404 grammes
(6.224 grains.) The solution was put into an inverted [p221] jar,
over mercury, and oxygen gas gradually passed in until absorption
ceased, and then the liquid containing the precipitated indigo was
evaporated to dryness at 212°. The weight of the substance was
increased to 0.047, _i. e._ 11.5 per cent.
Not having obtained indigogene _perfectly_ pure, M. Liebeg did not
attempt to analyze it for the ultimate composition. He remarks,
that indigo is, perhaps, the only organic body from which one of
its constituent parts may be taken without total decomposition; and
which, by oxidation, passes to the state of an indifferent body,
having much analogy with peroxides.—_Ann. de Chimie_, xxxv. 269.
39. _On the mutual Action of Ethers, and other Substances_.—From
experiments made by M. Henry, he concludes that when metals easily
oxidizable, or oxides which unite with acetic acid, are put into
sulphuric ether, they produce larger or smaller quantities of
acetates, probably, not by decomposing the sulphuric ether, but
the acetic ether which is always mixed with it; and that it is in
consequence of the saturation of the acetic acid set free from the
ether by this decomposition, that sulphuric ether does not redden
litmus paper when evaporated, whereas it acts differently when being
slightly heated, the quantity of acetic ether contained in it is
allowed to decompose by the action of the air.
Nitric and acetic ethers are described as being easily decomposed by
the action of many bodies without the assistance of heat, if aided by
time. Amongst the products of the action are the acids of the ethers,
acetates, and alcohol which dissolves the salts formed.—_Jour. de
Chimie Méd_.
40. _Faraday’s Chemical Manipulation_.—The kindness of a friend at
Bristol has pointed out to me an error in the directions relative to
alkalimetry, which I have given in the above work: this I am desirous
of correcting, and, by permission of Mr. Brande, have the opportunity
of doing so in the _Quarterly Journal of Science_.
The mistake, which arose from using the wrong specific gravity of two
that were required in calculation, occurs in the paragraphs (599,
600,) but fortunately is prevented from occasioning any experimental
error by the directions given in (602). The acid of specific gravity,
1.141, directed to be used, is too strong for the quantities marked
upon the tube. The substitution of one of specific gravity 1.127,
will correct the error, and may be obtained very nearly by mixing 19
parts, by weight, of strong oil of vitriol, with 81 parts of water.
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