With the exception of those containing large proportions of columbium, tantalum, and titanium, the rare earth minerals are easily decomposed by acids. The silicates, as a general rule, can be satisfactorily treated with hydrochloric acid in the ordinary way, but for large quantities, the use of sulphuric acid is more desirable. The more refractory minerals are completely decomposed by fused alkali hydrogen sulphate; sodium bisulphate is more suitable for this purpose than the potassium compound, the sodium double sulphates of the rare earth elements being more soluble than the potassium salts. Hydrofluoric acid also attacks the refractory minerals very readily; the rare earths, in this case, are left as the insoluble fluorides. After decomposition with sulphuric acid or bisulphate, the cold residue is extracted with water, the rare earth sulphates or double sulphates being removed in solution. Digestion with nitric acid may be necessary at this stage, if titanium, columbium, etc., are present; after filtration, the solution is evaporated to dryness, and the residue extracted with dilute hydrochloric acid. The solution is saturated with sulphuretted hydrogen to remove lead, copper, bismuth, molybdenum, etc., and treated in the usual way with ammonium chloride and ammonia. The precipitate is washed, and dissolved in hydrochloric acid, the solution heated to about 60°, and the rare earths precipitated by addition of excess of oxalic acid, which holds in solution any zirconium which may be present. In the presence of phosphates, _e.g._ in the treatment of monazite or xenotime, the precipitate of oxalates should be ignited to the oxides, these dissolved in acid, and a second precipitation with oxalic acid effected; this treatment is necessary to remove phosphoric acid completely. ~Preliminary examination of the earth mixture.~--Before a method of separation can be decided upon, some knowledge of the composition of the mixture to be treated must be obtained. The nature of the mineral used for the extraction will, as a rule, afford useful information. It is known that in some minerals the cerium group, in others the yttrium group, predominates more or less completely; certain minerals, also, are known to be rich in elements of one or another subgroup. An approximate knowledge of the relative proportions of the cerium, terbium, and yttrium groups will be afforded by a rough double sulphate separation; thorium, zirconium, and scandium come down with the cerium earths. For approximate separation, Urbain[185] proposes the use of the ethylsulphates. The yttrium elements can be quickly separated in an approximate manner by fractional precipitation of the hydroxides with magnesia. The successive fractions obtained by these methods are examined spectroscopically; from the results, the composition of each, and so of the original mixture, may be roughly deduced. [185] _Ann. Chim. Phys._ 1900, [vii.], ~19~, 184. THE SPECTRUM EXAMINATION