The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The intensity, and to some extent also the position, of bands in an
absorption spectrum may vary considerably, according to the conditions
employed. Of the various factors which must be considered, the
concentration of the solution, the thickness of the layer used, the
nature of the solvent, and of the acid radicle, and the presence of
other earths are the most important. The concentration of the solution,
and the thickness of the layer, which together constitute the Optical
Density, must be so adjusted that the absorption is neither too strong
nor too weak; in the first case the sharp bands tend to merge into broad
diffusion areas, and details are obscured, whilst in the second case the
presence of coloured compounds which do not show strong absorption bands
may be overlooked.
The nature of the acid radicle has considerable influence on the
position of the absorption maxima, the general rule being that the bands
are shifted towards the red end of the spectrum as the molecular weight
of the compound used increases. Naturally, also, the nature of the
solvent has an important effect, all the usual phenomena which must be
considered in the measurement of the physical properties of substances
in solution coming into play; electrolytic dissociation, hydration,
dissociation and the formation of complexes, for example, are all
important factors. The presence of colourless earths has also been found
to cause important differences. It follows, therefore, that for the
chemist, the absorption spectra can be considered as a valuable aid only
in detecting the presence or absence of the three elements which give
the strongest and most characteristic absorption bands, viz.
praseodymium, neodymium, and erbium, and that conclusions regarding the
quantitative composition of mixtures must be drawn with the utmost
caution.
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