The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
In his examination of the ceria earths in 1839, Mosander discovered a
new constituent, which he called Lanthana; the new oxide was removed in
solution when the ignited mixture was extracted with dilute nitric acid,
which leaves cerium dioxide undissolved. On examination, the new oxide
was found to be heterogeneous; by fractional precipitation with ammonia,
and subsequent recrystallisation of the sulphates, he obtained two
oxides, which he called respectively Lanthana (λανθανειν, to be hidden),
from the absence of colour and specific reactions, and Didymia,
(διδυμοι, twins) from their similarity and the occurrence of the two
together.
Samaria was isolated by Lecoq de Boisbaudran, in 1879, from a specimen
of didymia extracted from the mineral samarskite. Two years previously,
Delafontaine had shown that the didymia separated from this mineral was
not spectroscopically identical with the oxide obtained from other
sources, and in 1878 had isolated an oxide which he called Decipia; this
was shown later, however, to be a mixture of which samaria was one
component. The samaria obtained by de Boisbaudran was by no means pure,
being associated with terbia earths; several investigators claimed to
have separated from it new oxides, most of these being proved afterwards
to have been more or less impure specimens of Europia.
In 1885, Auer von Welsbach[238] employed for the first time the method
which has now become of paramount importance for the separation of the
cerium group, viz. the fractional crystallisation of the double
nitrates. By this method he succeeded in resolving Mosander’s didymia
into two new oxides, for which he proposed the names Praseodidymia
(πρασινος, leek-green), from the colour of the salts, and Neodidymia
respectively; the shorter names praseodymia and neodymia are, however,
now generally adopted.
[238] _Monats._ 1885, ~6~, 477; _Sitzungsber. kaiserl. Akad. Wiss.
Wien_, 1885, ~92~, II, 317.
[Illustration: ~GROUP A~
MIXED DOUBLE NITRATES.
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