The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The element gives the white _sesquioxide_, Tb₂O₃, and colourless
salts.[345] The _peroxide_, of which the composition corresponds
approximately to the formula Tb₄O₇, is obtained as a brownish-black
powder by ignition of suitable salts. Its presence, even in small
quantities, gives so deep a colouration to the other earths that some
kind of salt formation seems probable. It is insoluble in cold acids; it
dissolves in hot nitric acid with evolution of oxygen, forming a
solution from which the _nitrate_, Tb(NO₃)₃,6H₂O, melting at 89·3°,
separates on cooling. In hot hydrochloric acid, the peroxide dissolves
with evolution of chlorine, forming solutions from which the _chloride_,
TbCl₃,6H₂O, can be isolated with difficulty; this salt is extremely
deliquescent, and easily forms supersaturated solutions. The _sulphate_,
Tb₂(SO₄)₃,8H₂O, can be precipitated from a sulphuric acid solution of
the oxide by addition of considerable quantities of alcohol; it is
isomorphous with the other sulphate octohydrates, and is completely
dehydrated at 360°.
[345] The terbium compounds here described have been prepared by
Urbain (_loc. cit._) from carefully purified material; other compounds
have been described by Potratz (_Chem. News_, 1905, ~92~, 3), but her
material contained a large proportion of gadolinium.
~Atomic Weight.~--The value adopted by the International Committee is
159·2, which was obtained by Urbain in 1905 (_loc. cit._) from the
ratio Tb₂(SO₄)₃,8H₂O : Tb₂(SO₄)₃. This is the only determination on
which reliance can be placed, as the material of the earlier workers was
seldom even approximately pure.
~Detection.~--Solutions of terbium salts show only one band in the
visible spectrum, at 487·7 in the blue. This band was observed by
Lecoq de Boisbaudran in a specimen of terbia containing dysprosia, and
assumed by him to belong to a new element, Z_{δ} (_loc. cit._) In the
ultraviolet nine absorption bands have been observed (Urbain, _loc.
cit._)
The spark spectrum shows the lines observed by Demarçay in 1900, and
attributed by him to the new element Γ. Lecoq de Boisbaudran’s element
Z_{β} showed a green fluorescence with the reversed spark, a
phenomenon which Urbain has found to be exhibited by pure terbium
compounds.
The arc spectrum of Urbain’s pure terbia was examined by
Eberhard[346]--see also Exner and Haschek, and Eder and Valenta.[347]
The element may be detected in minerals and earth mixtures by the
following lines:
3523·82
3676·52
3703·05
3704·01
4005·62
4278·71
The chief lines in the arc spectrum (Exner and Haschek) are the
following:
3324·53
3509·34
3531·86
3561·90
3568·69
3600·60
3628·53
3650·60
3659·02
3704·10
3711·91
3848·90
3874·33
3899·34
3925·60
3939·75
3977·01
3982·07
4005·70
4012·99
4278·70
4752·69
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account