The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The amorphous metal is a dark powder, which when washed with water on
the filter paper passes through as a dark blue colloidal solution; it
burns readily when heated in the air. According to Wedekind and
Lewis,[459] amorphous zirconium is really the colloidal form of the
metal. The fused metal is very hard (7-8, Mohs’ scale--it scratches
quartz but not topaz) and very brittle; it has the density 6·4, and is
of a whitish colour, with good metallic lustre on freshly broken
surfaces. The atomic heat is abnormally high, being approximately 7·3;
the element is paramagnetic. The melting-point was given by Wedekind
and Lewis[460] as 2330°-2380°, but later work of the former author[461]
gives the much lower value of 1530°, which seems more probable in view
of the fact that the element cannot be employed for electric lamp
filaments (see p. 322).
[459] _Ibid._ 1910, ~371~, 367.
[460] Weiss and Neumann, _loc. cit._; also Wedekind, _loc. cit._
[461] _Annalen_, 1913, ~395~, 149.
Metallic zirconium is highly resistant to acids; it is attacked only by
hydrofluoric acid and by aqua regia. In the compact form it burns in the
air only at very high temperatures, though when powdered it glows in the
air at a red heat, forming probably a mixture of lower oxides. It is
attacked by chlorine and by hydrogen chloride at a red heat, with
formation of the chloride; fused potash also oxidises it, with evolution
of hydrogen. When heated in a current of hydrogen at a red heat, it
forms the _hydride_, ZrH₂,[462] as a velvet-black powder, which burns
with an intense bluish flame in oxygen, forming the sesquioxide, Zr₂O₃.
When heated in nitrogen or ammonia, amorphous zirconium yields
_nitrides_, which are also obtained when any attempt is made to reduce
zirconium compounds to the metal in air. The most definite is the
compound Zr₂N₃,[462] which forms a bronze-coloured powder, resistant to
all mineral acids except hydrofluoric acid. Chlorine and bromine
transform this to the halide.
[462] Wedekind and Lewis, _Annalen_, 1910, ~371~, 367.
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