The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Mesothorium appears to be chemically identical with radium; since
monazite, like all other thorium-bearing minerals, contains uranium and
radium, the latter element is separated with the mesothorium, and
indeed, having a very much larger half-life period, constitutes by far
the greater part of such ‘mesothorium’ preparations. On account of the
great activity of the mesothorium products, the best preparations from
monazite, though estimated to contain only 1 per cent. of mesothorium to
99 per cent. radium, are said to be four times as active as pure radium
compounds. The chemical identity of the two products seems to preclude
any possibility of determining the physical properties and constants of
mesothorium.
The element radiothorium, which was discovered by Hahn in 1905, in the
mineral thorianite, is chemically identical with the parent element
thorium, but can be separated by means of the intermediate element,
mesothorium 1. The latter is readily separated by the sulphate
precipitation, and the radiothorium to which it gives rise may be
separated by precipitation with ammonia. Thorium is also chemically
identical with ionium, the parent of radium, and the thorium nitrate of
commerce therefore contains important quantities of ionium--important
that is, in view of the high radiating power of the latter element. The
study of these relationships constitutes one of the most important and
interesting fields in the province of radioactivity.
_The Metal._--Elementary thorium has not yet been obtained in the pure
state, owing to the ease with which it forms compounds and alloys with
all the common elements, and to its great affinity for oxygen; the high
melting-point also increases the difficulty of obtaining the pure metal.
Berzelius attempted to reduce the alkali double fluorides and double
chlorides with sodium or potassium; Nilson carried out the same reaction
in a closed iron cylinder, but his product still contained 20 per cent.
of thoria. Reduction of the oxide with magnesium is never complete, and
the carbon method gives only a mixture of carbide and metal.
Electrolytic methods give no better results, since the metal liberated
at the cathode always encloses oxide and other impurities. Moissan and
Hönigschmid in 1906, by heating the carefully purified anhydrous
chloride with sodium in a sealed glass tube from which air and moisture
had been removed, claim to have obtained a product containing only 3 per
cent. of the oxide. The element has recently been prepared in leaf form
by forcing the amorphous product into the bore of a copper tube,
hammering into sheets, and removing the copper by dilute nitric
acid.[475]
[475] v. Bolton, _Zeitsch. Elektrochem._ 1908, ~14~, 768.
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