The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
[491] _Vide_, _e.g._ Moeller, _E._ 124, 1893.
The effect of increasing or decreasing the ratio of the two oxides, and
the theories which have been advanced to account for the results, must
be referred to in a later chapter (_vide_ p. 294). It may be mentioned
here, however, that practically no other known mixture gives such
satisfactory results, though mantles have been manufactured of alumina
with small quantities of chromic oxide, and ‘inverted’ mantles made of
these oxides with zirconia have recently been advocated by Professor
Lewes,[492] an authority on gas lighting. Mixtures of alumina and
uranium oxide have also been patented, but no mantles appear to have
been manufactured according to the specifications. In this connection,
also, may be mentioned the various attempts to evade the Auer patents by
taking advantage of the ‘discovery’ of ‘new’ elements. One enterprising
firm, after having an account of a ‘new’ element, Lucium, inserted in a
well-known scientific periodical, put salts on the market, and proceeded
to manufacture mantles from what were proved by analysis to be cerium
compounds. Similar ‘new’ elements were Russium, Kosmium, and
Neo-kosmium, names which covered various mixtures of thorium and cerium
compounds with other salts.
[492] _Vide_ _D. R. P._ 218333 of January 1910.
After the introduction in 1891 of the final Auer mixture, progress
became rapid. The original mantles, made from cotton, had many
disadvantages; thus after being in use for some time they were found to
shrink considerably, with marked decrease in strength and light-giving
power. Once the success of the new form of lighting was assured,
numberless investigations were undertaken to lengthen the life and
increase the efficiency of the mantles. The most important of these were
connected with the endeavour to replace cotton by some fabric which on
ignition would leave the oxide skeleton in a harder, more coherent and
more elastic condition. The first great advance in this connection was
the introduction of Ramie fibre by Buhlmann in 1898. Ramie, China-grass,
or grass-cloth, as it is sometimes termed, is a fabric made from the
fibres of the tschuma plant of the Yang-tse-kiang valley and other parts
of Asia; mantles made from it last longer and maintain their efficiency
much better than the earlier cotton mantles, which they have very
largely displaced. The use of artificial silk was patented by De Mare in
1894, but his process was unworkable; it was an effort to adapt to the
purposes of incandescent lighting the nitro-cellulose process introduced
by Chardonnet in 1890 for the manufacture of artificial silk. In 1897 De
Lery and in 1900 Plaisetty made further efforts in this direction, and
finally in 1902-1903 the latter worked out a process by which mantles
were made directly from the spun fabric. These mantles are superior in
every way to the earlier ramie or cotton kinds, and are rapidly coming
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