The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The solution of cellulose by Schweitzer’s reagent is undoubtedly a
chemical action. Cellulose is to be regarded as a polyhydric alcohol,
with one or several atoms of hydrogen of the hydroxyl groups replaceable
by metals. According to Piest (_loc. cit._) a ‘Cupramine base’ is formed
by the replacement of this hydrogen by copper and the amino-group, NH₂.
The action of sodium hydroxide on cellulose, however, is generally
regarded rather as an additive reaction, the product, ‘alkali
cellulose,’ being usually written C₆H₁₀O₅,NaOH. A careful chemical
investigation alone can reveal the actual nature of the compound formed;
such an investigation, apart from its scientific interest, might yield
results of considerable technical importance.
~The Viscose Process.~--Shortly after the introduction of the Chardonnet
process, patents were taken out which protected a very cheap and simple
method of dissolving cellulose,[529] which had been discovered by two
well-known English authorities. Cross and Bevan. They found that
mercerisation, _i.e._ the action of the sodium hydroxide on cellulose,
produces a swollen, transparent mass, which very readily takes up carbon
disulphide. When exposed to the action of this liquid for three or four
hours, at ordinary temperatures, the mass swells further, gelatinising
and becoming soluble in water. On treatment with water, a yellowish,
extremely slimy solution is obtained, from which cellulose is
precipitated on prolonged standing, by heating, or by oxidation. The
substance is apparently a cellulose xanthate, and may be written
NaS·CS·O·C₆H₉O₄,NaOH.[530] On account of the extremely viscous nature of
the aqueous solution, Cross and Bevan gave it the name Viscoid.
[529] _Vide_, _e.g._ Cross, Bevan, and Beadle, _D. R. P._ 70999,
granted September, 1893.
[530] _Vide_ Beltzer, _Zeitsch. angew. Chem._ 1908, ~21~, 1731.
During the last few years this method of dissolving cellulose has been
employed in the manufacture of artificial silk, under the name ‘Viscose
Process.’ The product obtained is very suitable for the manufacture of
incandescent mantles, and is considerably cheaper than either the
Chardonnet or Pauly silk.
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