The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The fabrics prepared by the processes which have been mentioned above
are of great technical value. In lustre they far surpass natural silk,
and they take dyes very well, but owing to the ease with which they
tear, they cannot be woven alone for textiles, but are always used in
‘mixed’ materials. The acetate silk, which approaches the natural fibre
in strength, is not much less expensive. Whilst the price of natural
silk is roughly 35 francs per kilo. (approx. 13_s._ 3_d._ per lb.), the
costs of production of the artificial fabrics are--Chardonnet 15 frs.,
Pauly 12 frs., Viscose 7 frs. per kilo. (respectively 5_s._ 8_d._, 4_s._
6_d._, and 2_s._ 8_d._ per lb.). Artificial silk, however, has uses
distinct from the natural fibre, and is at present a competitor with it
in one or two small fields only. Thus the production of natural silk is
ten times that of artificial silk (50,000,000 kilos. per annum to
5,000,000 kilos.) in spite of the difference in price.
Artificial silk is very susceptible to the action of water, which
weakens it very considerably. Its resistance is said to be greatly
increased by the action of formaldehyde; the fabric is plunged into a
bath containing an aqueous solution of the aldehyde, to which a little
lactic acid has been added. The chemistry of the change is discussed at
length by Beltzer (_loc. cit._).
The threads of artificial silk far surpass in lightness those spun from
vegetable fibres. A thread of twenty strands weighing one pound
avoirdupois would be more than twenty miles long. At the same time the
filaments have not the irregular tubular structure of vegetable fibres,
but are solid cylinders. The fact that the filaments are continuous, so
that there is relatively little torsion in threads spun from them, gives
artificial silk its great advantage over the natural vegetable fibres
for the manufacture of mantles. For this purpose the Pauly or
Cuprammonium silk is most suitable, though Viscose silk is almost as
good; the fibre obtained by the Chardonnet process is not quite so
useful in this direction.
~The Manufacture of Mantles from Artificial Silk.~--Whilst the fabrics
made by the various processes outlined above are more expensive than the
cotton and ramie formerly exclusively used in the mantle industry, they
have the advantage, in addition to the fact that they produce better and
more lasting mantles, that they do not need the laborious and
troublesome process of washing which is so essential in the case of the
vegetable fibres. From the nature of the methods used in its
manufacture, artificial silk can contain no mineral residue; hence the
fabric is immediately ready for impregnation.
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