The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
A rather similar proposal[541] substitutes for ammonia an alkaline
solution of hydrogen peroxide, obtained by dissolving sodium peroxide in
water. After saturation for a minute or so, the fabric is wrung out and
dried, there being no necessity, according to the patent, for any
subsequent washing. The same company in an earlier patent[542] suggest a
fixing bath of ‘an alkali or amine with an acid which can form insoluble
basic double salts with the earth metals,’ the said salt to be
precipitated on the fibre, whilst an alkali or amine nitrate goes into
solution; acetic and benzoic acids and phenol are mentioned. Apparently
this process did not give satisfactory results. The same may be said of
the hypochlorite method of Visseaux.[543] Equally interesting, and
doubtless equally practical is the proposal[544] to treat the dried
impregnated mantle with ozone in a closed chamber, which possibly
inspired the even more original suggestion[545] that the fabric be first
washed in ozonised water, dried, then impregnated and dried, and finally
treated with ozone. According to yet another French patent,[546] the
impregnated and dried fabric is to be treated with an alcoholic solution
of hydrofluoric acid, which will give a viscous insoluble mixture of
thorium and cerium fluorides in the fabric, and at the same time will
remove any impurities. Another patent[547] proposes the use of hydrazine
and similar bases, cerium nitrate being added to the fixing solution.
[541] _D._ 247940, June, 1912; _F._ 430417, August, 1911.
[542] _F._ 403433, September, 1909, Bruno Co.
[543] _F._ 408807, February, 1910.
[544] _F._ 414700, June, 1910.
[545] _F._ 422643, January, 1911.
[546] _F._ 426156, April, 1911.
[547] _E._ 11904, 1909.
Innumerable suggestions have been made for fixing by means of ammonia
gas, or vapours of organic bases.[548] An English patent granted in
February 1910[549] protects ‘various improvements,’ which consist in
carrying out a preliminary treatment with steam, impregnation with the
solution of nitrates, conversion of nitrates into oxides either by steam
carrying ammonia, pyridine, etc., or by the action of these vapours
without steam in a vacuum, all in one chamber, which can be exhausted or
filled with various solutions or vapours as required.
[548] _Vide_, _e.g._ _D. R. P._ 199615 of June, 1908.
[549] _E._ 25549, 1908.
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