The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
~The Final Stages.~--The treatment of the fabric after impregnation and
fixing differs only slightly from that used for the impregnated ramie
and cotton products. The dried strips are cut into suitable lengths, and
the head is drawn together with asbestos and threaded across. No tulle
or gauze is required, the end being simply turned down before threading.
After the ordinary strengthening process for the head (_vide_ p. 296)
the process of manufacture was, until recently, finished, the goods
being sent out in the unburnt condition, on account of the difficulties
of collodinisation. These have now been overcome, so that the mantles
are burnt off and collodinised as usual. Burning off and shaping are now
frequently effected in one operation by machine; the nature of the
methods by which the fibre is made produces a uniform fabric, and if the
earlier processes are carefully carried out, a uniform product is
obtained, which is therefore suitable for machine treatment.
CHAPTER XXI
OTHER TECHNOLOGICAL USES OF THE CERIUM AND YTTRIUM ELEMENTS, ZIRCONIUM
AND THORIUM
The technical uses of the members of this group of the elements we are
considering, apart from the employment in the manufacture of
incandescent mantles, are at present very restricted. Innumerable
proposals for the employment of the compounds of cerium and the allied
metals, which are obtained in such large quantities as by-products in
the thorium industry, have been put forward, but the actual extent to
which they are utilised is so small that only an insignificant fraction
of the available quantities is annually required. In the metallic form,
a limited application is found for various alloys, _e.g._ the so-called
pyrophoric alloys, misch metal, and the magnesium and aluminium alloys.
Various compounds of the elements, as well as some alloys, have been
suggested for use in arc-lamp electrodes, and the use of the metals
themselves, as well as of various salts, for the manufacture of
flashlight powders, is protected by several patents. Investigations have
been made to determine the value of the oxides and sulphates as
catalysts in the contact process for the manufacture of sulphuric acid,
and one patent states that the yield obtained is equal to that given by
platinised asbestos. Cerium salts have been proposed for tanning, and in
the preparation of enamels; cerium sodium sulphate is used in the
catalytic oxidation of aniline to aniline black. The oxalate has a very
slight use in medicine. The oxidising power of ceric salts is of some
use in photography; ceric sulphate in acid solution is also said to be
an efficient oxidising agent for aromatic hydrocarbons. On account of
the deep colour of the higher oxide of praseodymium, didymium salts
find a limited application for marking textiles.
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