The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The titanium minerals of commercial importance are rutile and ilmenite
(_vide_ Part I. pp. 57 and 77). The former, the pure titanium dioxide,
is of fairly wide distribution, but ilmenite occurs in far greater
quantities, forming deposits of enormous dimensions, especially in
America, as, _e.g._ in New York Co. and Quebec. Owing to its high
melting-point and relatively low specific gravity, metallic titanium
can only be incorporated with molten steels with the greatest
difficulty, and for this reason alloys of titanium and iron, known
technically as ferro-titanium, are usually employed for the treatment of
steels. For the preparation of ferro-titanium, ilmenite of good quality
is as suitable as rutile, and, of course, far cheaper; hence the latter
is only employed for the preparation of titanium salts for use in
colouring and mordanting, and for titanium compounds for arc-lamp
electrodes, etc.
Various processes are employed for the manufacture of ferro-titanium
from ilmenite. In cases in which a considerable percentage of carbon is
not undesirable, for instance, where the alloy is required for the
treatment of cast iron or of high-carbon steel, the mineral is reduced
directly with carbon in an electric furnace; the ferro-titanium so
obtained usually contains from six to eight per cent. of carbon. For
pure iron-titanium alloys, the process worked out by Rossi[609] is used
in America almost entirely. Ilmenite is charged into a bath of molten
aluminium, heated electrically; the mineral is at once attacked, with
formation of iron, in which the titanium dissolves as reduction
proceeds. This process may also be used for reduction of rutile, if
scrap iron is added to the aluminium bath, to allow of the formation of
the required alloy. In Germany, the Goldschmidt or ‘thermite’ reaction
is largely employed; powdered ilmenite is intimately mixed with the
calculated quantity of aluminium powder, reduction being started as
usual by means of a fuse of magnesium ribbon imbedded in a small
quantity of barium peroxide.
[609] _Elect. chem. Ind._ 1903, ~1~, 523.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account