The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The carbide alone is a good conductor, and gives a very satisfactory
light,[636] but electrodes made from this compound without additions
have several disadvantages. The life is short, and the arc soon becomes
flickering and unsteady. A deposit of the badly conducting dioxide
gradually accumulates on the anode, and once the current has been
interrupted, this deposit renders it very difficult to strike the arc
again. These disadvantages are largely overcome by a series of
improvements recently patented in Germany by the Allgemeine
Elektrizitäts Gesellschaft of Berlin. Addition of small quantities--4·5
per cent.--of chromium carbide increases the length of life;[637] the
unsteadiness and flickering are greatly diminished by incorporation of
powdered coke, cryolite and fluorspar,[638] or better, of the
titanofluoride of calcium or cerium,[639] whilst the addition of finely
divided sulphur (or selenium or tellurium)[640] greatly reduces the
disadvantage due to the throwing off of incandescent particles. The
British Thomson-Houston Company patents a similar electrode,[641] in
which a carbon-mixture is used instead of coke, and the electrode is
manufactured with a carbon shell. For this purpose, the paste prepared
from the powdered mixture may be filled into a hollow carbon rod, or the
lightly baked pencil may be coated with pitch and heated to a high
temperature. The use of a mixture of cerium fluoride and tungstate, with
carbon and cryolite, is also said to prevent flickering.[642]
[636] Weedon, _Trans. Amer. El. chem. Soc._ 1911, ~16~, 217.
[637] _D. R. P._ 231231, February, 1911.
[638] _Ibid._ 233125, March, 1911.
[639] _Ibid._ 251837, October, 1912.
[640] _Ibid._ 234466, May, 1911.
[641] _E._ 6500, 1912.
[642] Guay, _U. S. P._ 1039522, September, 1912.
In arc lamps in which pencils containing titanium compounds are used,
the anode is generally made of copper, and is placed below the cathode,
the reverse being the case where carbon electrodes are employed. The
copper is inactive, and contributes nothing to the light; if the anode
be of suitable dimensions, it wears away very slowly, whereas the
cathode, containing the titanium compound, is rapidly consumed. In lamps
in which carbon electrodes are used, the light is emitted chiefly from
the extremities of the electrodes, the path of the arc being
comparatively non-luminous; the light has the familiar reddish-yellow
colour characteristic of the earlier forms of arc lamps. Where titanium
pencils are employed, however, the light is emitted almost entirely from
the arc itself, the electrodes contributing very little, and is of a
pure white colour, very different from that of the carbon lamp.
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