The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Stated as concisely as possible, the relationship is as follows: Each
member of this chemical series of continuously varying composition can
crystallise in two forms, which are the same for every member. The two
varieties at one end of the series are called euxenite and priorite, at
the other end polycrase and blomstrandine.
Thus, whilst euxenite and priorite, at the one end, and polycrase and
blomstrandine at the other, have the same compositions, euxenite and
polycrase have the same crystalline form, whilst priorite and
blomstrandine have the same second crystalline form.
All four minerals have the same bright black appearance, and bright
conchoidal fracture; they are all four isotropic, probably as a result
of hydration. All are orthorhombic, but the measurements for euxenite
and polycrase are different from those for blomstrandine and priorite.
The two latter are not so widely distributed as the two former.
Blomstrandine occurs at Hitterö, Arendal, and other localities in
Norway; priorite is found in Swaziland, South Africa.
The crystal system of the Polycrase-Euxenite series is orthorhombic, but
Dana gives slightly different axial ratios for the two minerals. This,
though Brögger gives the same values for both, is by no means
incompatible with isomorphism, as a glance at the axial ratios for the
minerals aragonite, strontianite, witherite, etc., of the series of the
orthorhombic carbonates, will show.
Brögger’s ratios for the two are _a_ : _b_ : _c_ = 0·3789 : 1 : 0·3527;
Dana gives for polycrase 0·3462 : 1 : 0·3124, for euxenite 0·364 : 1 :
0·303.
~Euxenite.~
This species occurs usually in the massive form as a bright
brownish-black mineral, of hardness 6¹⁄₂, and sp. gr. 4·6 to 5·0. The
crystals are prismatic in habit; the common forms are the pinakoids
_a_ {100} and _b_ {010}, the prism _m_ {110}, the unit pyramid _p_
{111}, and the dome {201}. Ramsay, Collie and Travers found no helium
in it; Boltwood found uranium, radium and helium, and Strutt found in
addition to these thorium. As early as 1879, Blomstrand had observed
zirconium in euxenite.
The mineral is infusible and with difficulty soluble in acids. It occurs
in many localities in Scandinavia (Hitterö, Arendal, Brevig, etc.), in
North Carolina, South Australia, etc. It was discovered by Scheerer at
Jölster, in Norway, in 1839.
Public-domain text, read in full here on John Shaqi.
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