The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
It is found at Bourg d’Oisans in Dauphiné, and in Norway, the Urals,
Brazil, etc. In Switzerland it occurs as the variety Wiserine, which was
at one time believed to be xenotime. It was named Octahedrite by de
Saussure, in 1796, from the prevailing habit, and Oisanite, from its
occurrence in Dauphiné, by Delamètherie, in 1797. The name anatase
(ανατασις = erection) was proposed by Haüy, being intended to denote
that the vertical axis (_c_ : _a_) is greater than that of rutile, the
other tetragonal modification of the dioxide.
~Brookite~, the third form of this compound, is orthorhombic.
_a_ : _b_ : _c_ = 0·8416 : 1 : 0·9444.
Common forms--the three pinakoids _a_ {100}, _b_ {010}, and _c_ {001},
prisms _m_ {110}, _l_ {210}, pyramids _e_ {122}, _z_ {122}, and
numerous others.
Angles--(100) ∧ (110) = 40° 5´; (001) ∧ (100) = 48° 18´; (001) ∧ (011)
= 43° 22´.
The habit is varied; it occurs usually in bipyramids with _e_ and _m_
or prismatic with _m_, _a_, and terminating pyramids. Cleavage ∥ _m_
indistinct, ∥ _c_ very poor.
Hardness 5¹⁄₂-6; sp. gr. 3·87-4·01. Lustre metallic. Colour brown to
reddish- and yellowish-brown and black. The optical behaviour is
interesting. The acute bisectrix is perpendicular to _a_ (100), but
while for red light the plane of the optic axes is (001), for blue it
is (010); for an intermediate light, therefore (λ = 5550 µµ), the
mineral appears uniaxial.
The chief localities are Bourg d’Oisans, Miask, the St. Gothard, the
Tyrol, Magnet Cove in Arkansas, and Tremadoc in Wales.
Titanium dioxide can be obtained crystalline by the action of steam on
titanium tetrafluoride, TiF₄, at high temperatures; it is stated that by
varying the temperature of the reaction, any one of the three
crystalline modifications can be obtained.
* * * * *
The only other minerals which need be mentioned in this class (see list)
are:
_Zirkelite_, a complicated mixture of oxides, in which thoria, zirconia,
and titanium dioxide act as acidic oxides, and
_Mackintoshite_, a mixture of several oxides, of which those of thorium
and uranium are the most important.
(_b_) THE CARBONATES
~Lanthanite~, Hydrocerite.--This mineral is a carbonate of ceria earths,
chiefly lanthana, of the formula La₂(CO₃)₃,9H₂O.
Orthorhombic; _a_ : _b_ : _c_ = 0·9528 : 1 : 0·9023. Common forms--the
pinakoids _a_ {100} and _c_ {001}, with _m_ {110} and _o_ {111}.
Angles--(100) ∧ (110) = 43° 37´; (001) ∧ (101) = 43° 26¹⁄₂´; (001) ∧
(011) = 42° 3¹⁄₂´.
Habit tabular, parallel to _c_; cleavage perfect, ∥ _c_.
Double refraction negative; optic axis plane _a_ (100).
Usually amorphous, being probably an alteration product of a mineral
rich in lanthanum. Hardness 2; sp. gr. 2·6-2·7.
Colour white to yellowish-white, usually opaque; infusible before the
blowpipe (being converted to the oxide), readily soluble in acids.
Public-domain text, read in full here on John Shaqi.
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