The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Lanthanite occurs with cerite at Bastnäs, and at Bethlehem,
Pennsylvania.
Morton[94] states that he prepared a crystalline didymium carbonate in
the laboratory, of the formula Di₂(CO₃)₃,8H₂O, which was isomorphous
with lanthanite; he concluded that the latter had only eight instead of
nine molecules of water.
[94] See abstract in _Zeitsch. Kryst. Min._ 1886-87, ~12~, 518.
~Parisite~ (~Synchisite~), and ~Cordylite~.--_Parisite_ is a
fluocarbonate of calcium and cerium metals; _Cordylite_ is an analogous
compound in which barium replaces calcium, and is isomorphous with
Parisite. The formula of Parisite is CaR₂F₂(CO₃)₃, where R = cerium
metals. Groth formulates this as (CaF)(RF)R(CO₃)₃, Penfield and Warren
as (RF)₂Ca(CO₃)₃, whilst Schilling gives Ce₂(CO₃)₃,CaF₂. Analogous
formulæ may be proposed for Cordylite, BaR₂F₂(CO₃)₃. Since the two
minerals are very similar in crystallographic properties, one
description will be sufficient for both. The following are Dana’s data
for Parisite:
Hexagonal, _c_ = 3·2891. (0001) ∧ (101̅1) = 75° 15´.
Forms are extremely numerous, and have remarkably high indices. Among
the simplest are the base _c_ {0001}, the prism _m_ {101̅0}, pyramids
_q_ {101̅2}, and _h_ {112̅2}; the other forms are chiefly rhombohedra
and pyramids. The usual habit is that of an acute double hexagonal
pyramid, with form _o_ {202̅1}, terminated by _c_. Cleavage ∥ _c_,
perfect.
It is brownish-yellow to red. Hardness 4¹⁄₂; sp. gr. 4·36.
The double refraction is strong, positive. Soluble in hydrochloric
acid with effervescence.
Both minerals are characteristic pneumatolytic species of the
riebeckite-ægirine rocks. Parisite was discovered by Paris in the
emerald mines of the Muso valley, Colombia, in 1835, and first correctly
analysed by Bunsen in 1845. Before the blowpipe it glows, remaining
infusible (the glow does not appear to have been investigated in this
case).
_Cordylite_ was discovered by Flink in 1900, in Greenland.
It is yellow to brownish-yellow and colourless. Hardness 4¹⁄₂; sp. gr.
4·31. Before the blowpipe it decrepitates, and is infusible; moistened
with hydrochloric acid, it gives the characteristic barium flame.
The so-called Synchisite was discovered by Nordenskiöld who correctly
described it as Parisite. Flink found it in Greenland, and announced it
as a new species, with the formula R₂F₂Ca₂(CO₃)₄, _i.e._ the formula for
parisite plus one molecule of calcium carbonate, CaCO₃. From its
extraordinary resemblance to parisite in physical and crystallographic
properties, Palache and Warren[95] believe that the specimens selected
by Flink for analysis must have consisted, in reality, of parisite with
admixed calcium carbonate. This conclusion has now been confirmed by
Quercigh, by a careful comparison of the optical properties.[96] The
minerals are usually found together, the chief localities being S.
Norway, the gold districts of the Urals, Narsarsuk in S. Greenland, and
Montana, U.S.A.
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