The question of the origin of helium in minerals is, however, not definitely settled, for several anomalous cases are known. Thus the yttria silicate, Thalénite (_q.v._), contains quantities of helium, but no uranium or thorium is given in the analyses. Similarly, Risörite contains a relatively large quantity of helium, but only traces of uranium and thorium. In the last mineral, the active constituent is precipitated with the lead, so that no radio-thorium appears to be present. Further, Thomsen analysed a fluorspar from Ivitgut in Greenland which he found to contain 27 c.c. of helium per kilogram. This specimen contains no uranium, but gives off the thorium emanation in quantities which suggest the presence of radio-thorium; moderate quantities of thorium are also present. Since the α particle has been definitely identified as a positively charged helium atom, it appears certain that disintegration in all three series (uranium, actinium, and thorium series) produces helium, and a mineral containing a member of any of these series (which gives α rays or α ray-giving products) would also contain helium. Even so, there is a case in which the helium content is anomalous, if not altogether beyond explanation at the present stage. In examining a large number of minerals for helium, Strutt[136] found that some samples of beryl, a beryllium aluminium silicate, contain a relatively very large amount of helium, but only traces of thorium, and was altogether inactive. The absence of any active constituent renders untenable the ordinary explanations of the presence of such a surprising quantity of helium. Boltwood has put forward a suggestion which in the present state of our knowledge must be regarded as a provisional explanation. He conceives that in the concentration of beryllium from the parent magma, it may have become associated with some short-lived intermediate radioactive element, which had been altogether separated from its long-lived parent element in the process of concentration; this intermediate element, having collected in the crystallised beryl, decayed completely in the course of the great period which must have elapsed, leaving the helium to which it had given rise during its disintegration enclosed in the mineral. It is difficult to see how two substances which must be so intimately connected as a parent-element and its product could be completely separated in the process of cooling of a magma; but since so little is known of the process of crystallisation of minerals, the suggestion can hardly be rejected on geological grounds. In any case, we have here only one strongly marked exception to the very definite rule that in all cases in which helium occurs in minerals, it is accompanied by and undoubtedly produced from, a radioactive element or elements; and in the majority of cases, the helium in minerals is produced by disintegration of uranium or thorium and their products. [136] _Proc. Roy. Soc._ 1908, A, ~80~, 572.