The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
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The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Strutt’s earlier work on the helium ratio was made with phosphate
minerals (coprolites and fossil bones) of known ages. The ratios found
were not in order of age, the minerals being very permeable, so that
helium had probably been lost. He next turned his attention to igneous
rocks, and selected zircon for the work. Here he obtained some sort of
regularity in the order of age and the order given by the ratio, and
assumed that if helium were lost at all, it must be lost in roughly
proportional amounts by reason of the similarity in conditions.
Geological criticism tends to lessen the trustworthiness of the
conclusions; it is pointed out that the age of a specimen of zircon is
not necessarily that of the rock in which it occurs, for zircon is an
extremely stable mineral, and might survive unchanged several fusions
and re-crystallisations of the magma. Strutt replies to this that at the
temperature of fusion of a rock, zircon would certainly give up its
accumulated helium, so that the age determined from the helium content
would be that of the last fusion, _i.e._ the age as given by geological
data. On the other hand, our ignorance of the real mechanism of the
crystallisation of a magma, and especially of the amount and effect of
the pressures obtaining, robs this reply of its force, and the objection
must be counted valid.
In still later work Strutt used sphene and thorianite, and his results
agree as well as can be expected. The sphenes used were all from Archæan
rocks, except one, which was from a Tertiary volcanic deposit of the
Laacher See, near Coblenz (the lake is in the crater of an extinct
volcano). In this case the helium ratio was very much smaller (about
¹⁄₄₀₀₀ of the values for Archæan rocks) indicating the (comparatively)
extremely recent formation of the deposit.
The most recent results in the study of radioactivity point to the
conclusion that elements which differ in atomic weight and radioactive
properties may be chemically identical, or at least chemically
inseparable; such elements have been termed isotopes. The end product of
the thorium series of radio-elements should have an atomic weight of
about 208·4, and it has been suggested that the element actually
produced in this series of changes may be bismuth. The latest results,
however, rather point to the conclusion that disintegration in the
thorium series gives rise to an isotope of lead. If this hypothesis be
true, the lead derived from a mineral rich in thorium and poor in
uranium should have an atomic weight appreciably higher than that of
ordinary lead. Experiments to test this conclusion have recently been
carried out by Soddy and Hyman.[145]
[145] _Proc. Chem. Soc._ 1914, ~30~, 134.
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