The Scientific Monthly, October to December, 1915Various
Science
The Scientific Monthly, October to December, 1915
Various
Science -- Periodicals; Technology -- Periodicals
Volta apparently thought that the current was not only set up
by the contact of the two metals of a pair, but that it was
kept up by the mutual action of the metals on each other. He
accordingly made no attempt to discover whether any changes
took place in his circuit while the current was being
generated. The chemical action on his metals and the
dissociation in his electrolyte seem to have entirely escaped
his attention. At least, he did not attach enough importance to
them to mention them anywhere in his description of his
apparatus.
In the meantime a chemical explanation of the phenomena
observed by Galvani had been proposed in 1792 by Fabroni, a
physicist of Florence. After discussing the Sulzer phenomenon
already mentioned in this paper, Fabroni argues that the
peculiar taste caused by bringing the two metals into contact
while on the tongue is due to a chemical, rather than to an
electrical, action. He then discusses the different chemical
behavior of metals when taken singly and when placed in contact
with other metals. He says:[2]
[2] The following quotations from Fabroni have been translated
by the present writer from the German of Ostwald's
"Elektrochemie," pp. 103, ff.
I have already frequently observed that fluid mercury retains
its beautiful metallic luster for a long time when by itself;
but as soon as it is amalgamated with any other metal it
becomes rapidly dim or oxidized, and in consequence of its
continuous oxidation increases in weight.
I have preserved pure tin for many years without its changing
its silvery luster, while different alloys of this metal which
I have prepared for technical purposes have behaved quite
otherwise.
I have seen in the museum at Cortonne Etrusean inscriptions
upon plates of pure lead which are perfectly preserved to this
day' although they date from very ancient times; on the other
hand, I have found with astonishment in the gallery of Florence
that the so-called "piombi" or leaden medallions of different
popes, in which tin and possibly some arsenic have been mixed
to make them harder and more beautiful, have fallen completely
to white powder, or have changed to their oxides, though they
were wrapped in paper and preserved in drawers.
In the same way I have observed that the alloy which was used
for soldering the copper plates upon the movable roof of the
observatory at Florence has changed rapidly and in places of
contact with the copper plates has gone over into a white
oxide.
I have heard also in England that the iron nails which were
formerly used for fastening the copper plates of the sheathing
of ships were attacked on account of contact, and that the
holes became enlarged until they would slip over the heads of
the nails which held them in position.
It seems to me that this is sufficient to show that the metals
in these cases exert a mutual influence upon each other, and
that to this must be ascribed the cause of the phenomena which
they show by their combination or contact.
Public-domain text, read in full here on John Shaqi.
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