The Scientific Monthly, October to December, 1915Various
Science
The Scientific Monthly, October to December, 1915
Various
Science -- Periodicals; Technology -- Periodicals
Similarly, tin exists under two stable forms, white and gray,
the one above, the other below the transitional point, which
is, in this case, 18 degrees C. At this temperature white tin
is in a metastable condition, and transforms into the gray
variety. The transformation goes on, then, at ordinary
temperatures, but, fortunately for us as users of tin
implements, very slowly. Its velocity can be increased,
however, by lowering the temperature, on which, then, not only
the transformation itself, but its rate depends.
In this connection may be mentioned cholesteryl acetate and
benzoate and other substances which possess two crystalline
phases, one of which is liquid, unlike other liquids, however,
in being anisotropic. As in the preceding cases, these phases
are expressions of equilibrium at different temperatures.
Especially instructive facts are afforded by the alloys of iron
and carbon. Iron, or ferrite, exists under three forms: as
alpha ferrite below 760 degrees, as beta ferrite between 760
degrees and 900 degrees, and as gamma ferrite above 900
degrees. Only the last is able to hold carbon in solid
solution. The alloys of iron and carbon exist under several
forms. Pearlite is a heterogeneous mixture containing 0.8 per
cent. carbon. When heated to 670 degrees, it becomes
homogeneous, an amount of carbon up to two per cent. dissolves
in the iron, and hard steel or martensite is formed. In
appearance, however, the two forms are so nearly identical as
to be discriminated only by careful microscopical examination.
Cementite is a definite compound of iron and carbon represented
by the formula Fe<3 subscript>C.
When cooled slowly below 670 degrees, martensite yields a
heterogeneous mixture of pearlite and ferrite (or cementite, if
the original mixture contained between 0.8 per cent. and two
per cent. of carbon). Soft steels and wrought iron are thus
obtained. When cooled rapidly, however, as in the tempering of
steel, martensite remains a homogeneous solid solution, or hard
steel.
One can not fail to notice the remarkable parallel between
these facts and the behavior of Hydra in the presence of
strychnine. In both cases new positions of stability are
reached by modifying the original conditions of stability; and
in both, the old positions of stability are regained only by
returns to the original conditions of stability so gradual as
to afford time sufficient for the necessary transformations in
the systems themselves.
The forms which both organic and inorganic systems assume thus
appear to be functions of the conditions in which they exist.
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