The Scientific Monthly, October to December, 1915Various
Science
The Scientific Monthly, October to December, 1915
Various
Science -- Periodicals; Technology -- Periodicals
Observing that the ether was quite turbid and wishing to learn
the cause, a drop or two was allowed to evaporate on a glass
slide. Examining the residue with a microscope it was found to
consist of innumerable raphides or needle-like crystals. Some
of the ether was then run through a filter. The filtrate was
clear. An examination showed it to be entirely free from
raphides, and it had lost every trace of its acridity. The
untreated acrid juice of the Indian turnip, calla, and other
plants of the same family was then filtered and in every
instance the filtered juice was bland and had lost every trace
of its acridity. These tests and others that need not be
mentioned, proved conclusively that the acridity of various
species of the Arum family was not due to a volatile principle,
but was due to the needle-shaped crystals found so abundantly
in these plants.
Several questions yet remained to be answered. (1) If these
needle-like crystals or raphides are the cause of the acridity
of the plants just mentioned, why do they not produce the same
effect in the fuchsia, tradescantia and other plants where they
are known to be just as abundant? (2) Why does the Indian
turnip lose its acridity on being heated? (3) Why does the
dried Indian turnip lose its acridity?
It was first thought that the raphides found in plants having
no acridity, might be of different chemical composition than
those which produce this effect.
A chemical examination proved beyond question that the raphides
were of the same composition. The needle-shaped crystals in all
the plants selected for study were composed of calcium oxalate.
The crystals, found in grape, rhubarb, fuchsia and tradescantia
were identical in form, fineness and chemical composition with
those found in the plants of the Arum family. How then account
for the painfully striking effect in one case and the
non-effect in the other? This was the perplexing question.
In expressing some juice from the stems and leaves of the
fuchsia and tradescantia it was found to be quite unlike that
of the Indian turnip and calla. The juice of the latter was
clear and limpid; that of the former quite thick and
mucilaginous. There was no difference as to the abundance of
crystals revealed by the microscope.
After diluting the ropy, mucilaginous juice with water, and
shaking it thoroughly with an equal volume of ether, there was
no turbidity seen in the supernatent ether. Allowing a few
drops of the ether to evaporate scarcely any crystals could be
found. Practically none of them had been removed from the
insoluble mucilaginous covering. Here and there an isolated
specimen was all that could be seen. So closely were these
small crystals enveloped with the mucilaginous matter that it
was almost impossible to separate or dissect them from it.
It was now easy to explain why certain plants whose cells were
crowded with raphides were bland to the taste, while other
plants with the same crystals were extremely acrid.
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