The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
The probability that one element might be changed into another was
increased by the demonstration of the connexions between uranium and
radium. The metal uranium has been classed with the elements since it
was isolated in 1840. In 1896, Becquerel found that compounds of
uranium, and also the metal itself, are radio-active. In the light of
what is now known about radio-activity, it is necessary to suppose
that some of the minute particles of uranium emit particles lighter
than themselves, and change into some substance, or substances,
different from uranium; in other words, it is necessary to suppose
that some particles of uranium are spontaneously disintegrating.
This supposition is confirmed by the fact, experimentally proved,
that uranium emits [alpha]-rays, that is, atoms of helium, and
produces a substance known as uranium X. Uranium X is itself
radio-active; it emits [beta]-rays, that is, it gives off electrons.
Inasmuch as all minerals which contain compounds of uranium contain
compounds of radium also, it is probable that radium is one of the
disintegration-products of uranium. The rate of decay of radium may be
roughly expressed by saying that, if a quantity of radium were kept
for ten thousand years, only about one per cent. of the original
quantity would then remain unchanged. Even if it were assumed that at
a remote time the earth's crust contained considerable quantities of
radium compounds, it is certain that they would have completely
disappeared long ago, had not compounds of radium been reproduced from
other materials. Again, the most likely hypothesis is that compounds
of radium are being produced from compounds of uranium.
Uranium is a substance which, after being rightly classed with the
elements for more than half a century, because it had not been
separated into unlike parts, must now be classed with the radium-like
substances which disintegrate spontaneously, although it differs from
other radio-active substances in that its rate of change is almost
infinitively slower than that of any of them, except thorium.[12]
Thorium, a very rare metal, is the second of the seventy-five or
eighty elements known when radio-activity was discovered, which has
been found to undergo spontaneous disintegration with the emission of
rays. The rate of change of thorium is considerably slower than that
of uranium.[13] None of the other substances placed in the class of
elements is radio-active.
[12] The life-period of uranium is probably about eight
thousand million years.
[13] The life-period of thorium is possibly about forty
thousand million years.
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