The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
Many experimenters had noticed that gases (or airs, as they were
called up till near the end of the 18th century) are generally
produced when metals are dissolving in acids. Most of those who
noticed this said that the gases came from the dissolving metals;
Lavoisier said they were produced by the decomposition of the acids.
In order to study the interaction of nitric acid and mercury,
Lavoisier caused a weighed quantity of the metal to react with a
weighed quantity of the acid, and collected the gas which was
produced; when all the metal had dissolved, he evaporated the liquid
until a white solid was obtained; he heated this solid until it was
changed to the red substance called, at that time, _red precipitate_,
and collected the gas produced. Finally, Lavoisier strongly heated the
red precipitate; it changed to a gas, which he collected, and mercury,
which he weighed.
The weight of the mercury obtained by Lavoisier at the end of this
series of changes was the same, less a few grains, as the weight of
the mercury which he had caused to react with the nitric acid. The gas
obtained during the solution of the metal in the acid, and during the
decomposition of the white solid by heat, was the same as a gas which
had been prepared by Priestley and called by him _nitrous air_; and
the gas obtained by heating the red precipitate was found to be
oxygen. Lavoisier then mixed measured volumes of oxygen and "nitrous
air," standing over water; a red gas was formed, and dissolved in the
water, and Lavoisier proved that the water now contained nitric acid.
The conclusions regarding the composition of nitric acid drawn by
Lavoisier from these experiments was, that "nitric acid is nothing
else than _nitrous air_, combined with almost its own volume of the
purest part of atmospheric air, and a considerable quantity of water."
Lavoisier supposed that the stages in the complete reaction between
mercury and nitric acid were these: the withdrawal of oxygen from the
acid by the mercury, and the union of the compound of mercury and
oxygen thus formed with the constituents of the acid which remained
when part of its oxygen was taken away. The removal of oxygen from
nitric acid by the mercury produced _nitrous air_; when the product of
the union of the oxide of mercury and the nitric acid deprived of part
of its oxygen was heated, more nitrous air was given off, and oxide of
mercury remained, and was decomposed, at a higher temperature, into
mercury and oxygen.
Lavoisier thought of these reactions as the tearing asunder, by
mercury, of nitric acid into definite quantities of its three
components, themselves distinct substances, nitrous air, water, and
oxygen; and the combination of the mercury with a certain measurable
quantity of one of these components, namely, oxygen, followed by the
union of this compound of mercury and oxygen with what remained of the
components of nitric acid.
Public-domain text, read in full here on John Shaqi.
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