The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made ApparatusSt. John, Thomas M. (Thomas Matthew)
Science
The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made Apparatus
(B) Replace the plates in the cell, and connect them with the
15-turn coil of G V, placed N and S. Allow the circuit to
remain closed for half an hour, and record the position of the
needle every 5 minutes.
(C) Again wash, dry with a cloth without rubbing, and weigh
both the zinc and copper. Compare the new weights with those
found in (A).
_=285. Chemical Action in the Two-Fluid Cell.=_ In this form of cell
the hydrogen is not allowed to collect upon the copper plate. The
action inside of P C is like that explained in § 270, hydrogen being
set free. As soon as this hydrogen (H_{2}) comes in contact with the
copper sulphate (CuSO_{4}), and it begins to do this in the walls of
P C, a new chemical reaction takes place. Hydrogen has a stronger
attraction for SO_{4} than Cu has, so it unites with the SO_{4},
forming H_{2}SO_{4} (sulphuric acid), and this at the same time throws
out the Cu bodily. This Cu is then free, instead of hydrogen, to be
deposited upon the copper plate. The current is constant, as there is
no polarization.
_=286. Various Galvanic Cells; Open and Closed Circuit Cells.=_ There
is no one form of cell that is best for all kinds of work. If momentary
currents only are wanted, such as for bells, telephones, etc., in which
the cell has plenty of time to rest, _open circuit_ cells are used.
These cells polarize, however, when the circuit has to be closed for
any length of time. This form of cell is always ready for use, and may
not need attention for months at a time. The most common forms of the
open circuit cells are the _Leclanché_ (§ 287) and _dry_ cell (§ 288).
Open circuit cells polarize quickly, because the depolarizer (§ 280) is
slow in destroying the hydrogen.
When a strong current is needed for a considerable time, such as for
telegraph lines, motors, etc., a _closed circuit_ cell is necessary.
The depolarization must be rapid and constant. The _bichromate_ (§ 289)
and the _Daniell_ cell (§ 290) are very common forms of closed circuit
cells. (See, also, Storage Cells.)
=287. The Leclanché Cell= is an open circuit cell in which
carbon and zinc are the plates. The carbon is surrounded
with dioxide of manganese, a depolarizer; the two are either
packed together in a porous cup, or the latter is compressed
into blocks, which are fastened to the carbon. The porous cup
stands in a jar containing a solution of sal ammoniac (ammonium
chloride), which acts as the exciting fluid, and in which
stands a zinc rod. The zinc is not acted upon when the circuit
is open. The hydrogen given off by the decomposition of the
ammonium chloride is destroyed by the oxygen contained in the
manganese dioxide. The E. M. F. is nearly 1.5 volts.
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