In South America, the Chilian lead mine of Mina Grande, near Coquimbo,
is renowned for its extreme richness, and Brazil has considerable veins
of galena, in the province of Minas Geraes; but probably the United
States of North America (Wisconsin, Arkansas, Iowa, Illinois), possess
the largest galena deposits in the world. In Wisconsin, they extend all
over a vast territory of more than 4,000 square miles. As yet the works
are conducted in the most negligent manner, by a crowd of adventurers.
In winter, when the air in the pits is more salubrious, and agricultural
labour ceases, needy farmers, bankrupt traders, and thriftless artisans
flock from all parts to the lead country for the purpose of repairing
their broken fortunes. In summer when malaria renders the pits extremely
unhealthy, this nomadic population melts away like chaff before the
wind. Yet, in spite of the rough mode of extraction which prevails in
the American lead country, the mines of Iowa, Wisconsin, and Illinois
yielded about 20,000 tons of lead in 1866, and their produce is
constantly increasing.
In all lead mines, the galena often occurs in pieces so large that they
do not require to be separated from the veinstone by the processes of
stamping and washing. They are then called _pure ores_, and the most
simple preparation is sufficient to prepare them for the smelting
furnace. When the ore has been picked and so far prepared, it is first
roasted or heated in a reverberatory furnace, an operation which causes
the oxygen of the air to combine with the two elementary bodies of which
galena is composed. After undergoing this chemical change, the ore is
now mixed with coke, charcoal, or peat, and reduced by smelting in a
small blast furnace of a peculiar kind. Under the influence of heat, the
carbon of the coal, uniting with the oxygen of the ore, flies off in the
form of carbonic acid gas, while the metallic lead, which in the finer
ores amounts to 70 or 80 per cent., sinks to the bottom of the furnace.
Almost all the varieties of galena contain a greater or less proportion
of silver, which it is often found worth while to separate from them.
This process is at present effected according to a most ingenious
method, founded on the circumstance first noticed in the year 1829, by
the late H. L. Pattinson, of Newcastle-on-Tyne, that when lead
containing silver is melted in a suitable vessel, afterwards slowly
allowed to cool, and at the same time kept constantly stirred at a
certain temperature near the melting point of lead, crystals begin to
form. These, as rapidly as they are produced, sink to the bottom, and on
being removed are found to contain much less silver than the lead
originally melted. The still fluid portion, from which the crystals have
been removed, will at the same time be proportionally enriched. By
repeated meltings and crystallisations in a series of cast-iron pots
with fire-places beneath, the workman is thus able to deprive almost
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