On general principles the last rinsing should be with distilled water
and the glass surface should not be allowed to dry between this rinsing
and starting the silvering process, but the whole mirror should be kept
under water until the time for silvering. In Dr. Brashear’s process the
following two solutions are made up; first the reducing solution as
follows:
Rock candy, 20 parts by weight.
Strong nitric acid (spec. gr. 1.22), 1 part.
Alcohol, 20 parts.
Distilled water, 200 parts.
This improves by keeping and if this preparation has to be hurried the
acid, sugar and distilled water should be boiled together and then the
alcohol added after the solution is cooled.
Second, make up the silvering solution in three distinct portions;
first the silver solution proper as follows:
1. 2 parts silver nitrate. 20 parts distilled water.
Second, the alkali solution as follows:
2. 1⅓ parts c.p. caustic potash. 20 parts distilled water.
Third, the reserve silver solution as follows:
3. ¼ part silver nitrate. 16 parts distilled water.
The working solution of silver is then prepared thus: Gradually add
to the silver solution No. 1 the strongest ammonia, slowly and with
constant stirring. At first the solution will turn dark brown and then
it will gradually clear up. Ammonia should be added only just to the
point necessary to clear the solution.
Then add No. 2, the alkali solution. Again the mixture will turn dark
brown and must be cautiously cleared once more with ammonia until it is
straw colored but clear of precipitate. Finally add No. 3, the reserve
solution, very cautiously with stirring until the solution grows
darker and begins to show traces of suspended matter which will not
stir out. Then filter the whole through absorbent cotton to free it of
precipitate and it is ready for use. One is then ready for the actual
silvering.
Now there are two ways of working the process, with the mirror face
up, or face down. The former is advantageous in allowing better
inspection of the surface as it forms, and also it permits the mirror
of a telescope to be silvered without removing it from the cell, as was
in fact done habitually in case of the big reflector of the Alleghany
Observatory where the conditions were such as to demand re-silvering
once a month. The solution was kept in motion during the process by
rocking the telescope as a whole.
When silvering face up the mirror is made to form the bottom of the
silvering vessel, being fitted with a wrapping of strong paraffined
or waxed paper or cloth, wound several times around the rim of the
mirror and carried up perhaps half the thickness of the mirror to
form a retainer for the silvering solution. This band is firmly tied
around the edge of the mirror making a water tight joint. Ritchey uses
a copper band fitted to the edge of the mirror and drawn tight by
screws, and finishes making tight with paraffin and a warm iron.
Public-domain text, read in full here on John Shaqi.
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