Maxwell, and others after him, further shewed that no matter how many
kinds of molecules there may be mixed together in a gas, and no matter
how widely their weights may differ from one another, their repeated
collisions must ultimately establish a state of things in which big
molecules and little, light and heavy, all have the same average
energy. This is known as the theorem of equipartition of energy.
It does not mean that at any single instant all the molecules have
precisely the same energy; obviously such a state of things could not
continue for a moment, since the first collision between any pair of
molecules would upset it immediately. But on averaging the energy of
each molecule over a sufficiently long period of time—say a second,
which is a very long time indeed in the life of a molecule, being the
time in which at least a hundred million collisions occur—we shall find
that the average energy of all the molecules is the same, regardless of
their weights.
The same theorem can be stated in a slightly different form. Air
consists of a mixture of molecules of different kinds and of different
weights—molecules of helium which are very light, molecules of nitrogen
which are far heavier, each weighing as much as seven molecules of
helium, and the still heavier molecules of oxygen, each with the weight
of eight molecules of helium. In its alternative form, the theorem
tells us that at any instant the average energy of all the molecules
of helium, in spite of their light weights, is exactly equal to the
average energy of the molecules of nitrogen, and again each of these
is exactly equal to the average energy of the molecules of oxygen. The
lighter types of molecule make up for their small weights by their high
speeds of motion. Similar statements are of course true for any other
mixture of gases.
The truth of the theorem is confirmed observationally in a great
variety of ways. In 1846, Graham measured the relative speeds with
which the molecules of different kinds of gas moved, by observing the
rates at which they streamed through an orifice into a vacuum; these
proved to be such that the average energies of the various types of
molecules were precisely equal to one another. Even earlier than this,
Leslie and others had used this method to determine the relative
weights of different molecules, although without fully understanding
the underlying theory. Thus it may be accepted as a well-established
law of nature that no molecule is allowed permanently to retain more
energy than his fellows; in respect of their energies of motion, a
gas forms a perfectly organised communistic state in which a law,
which they cannot evade, compels the molecules to share their energies
equally and fairly.
Public-domain text, read in full here on John Shaqi.
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