AVAILABILITY OF ENERGY. The second law of thermodynamics rules out any
such possibility. Energy is indestructible as regards its amount, but
it continually changes in form, and generally speaking there are upward
and downward directions of change. It is the usual story—the downward
journey is easy, while the upward is either hard or impossible. As a
consequence, more energy passes in one direction than in the other.
For instance, both light and heat are forms of energy, and a million
ergs of light-energy can be transformed into a million ergs of heat
with the utmost ease; let the light fall on any cool, black surface,
and the thing is done. But the reverse transformation is impossible;
a million ergs which have once assumed the form of heat, can never
again assume the form of a million ergs of light. This is a special
example of the general principle that radiative energy tends always to
change into a form of longer, not shorter, wave-length. In general,
for instance, fluorescence increases the wave-length of the light; it
changes blue light into green, yellow or red, but not red light into
yellow, green or blue. Exceptions to the general principle are known,
but they are of special type, admitting of special explanations, and do
not affect the general principle.
It may be objected that the everyday act of lighting a fire disproves
all this. Has not the sun’s heat been stored up in the coal we burn,
and cannot we produce light by burning coal? The answer is that the
sun’s radiation is a mixture of both light and heat, and indeed
of radiation of all wave-lengths. What is stored up in the coal
is primarily the sun’s light and other radiation of still shorter
wave-length. When we burn coal we get some light, but not as much
as the sun originally put into the coal; we also get some heat, and
this is more than the amount of heat which was originally put in. On
balance, the net result of the whole transaction is that a certain
amount of light has been transformed into a certain amount of heat.
All this shews that we must learn to think of energy, not only in terms
of quantity, but also in terms of quality. Its total quantity remains
always the same; this is the first law of thermodynamics. But its
quality changes, and tends to change always in the same direction.
Turnstiles are set up between the different qualities of energy; the
passage is easy in one direction, impossible in the other. A human
crowd may contrive to find a way round without jumping over turnstiles,
but in nature there is no way round; this is the second law of
thermodynamics. Energy flows always in the same direction, as surely as
water flows downhill.
Public-domain text, read in full here on John Shaqi.
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