Similar changes are found to occur in the properties of thin layers of
liquid. A teaspoonful of soup will cover the bottom of a soup plate,
but a single drop of soup will only make an untidy splash. In some
cases it is possible to measure the exact thickness of layer at which
the properties of liquids begin to change. In 1890 Lord Rayleigh found
that thin films of olive oil floating on water changed their properties
entirely as soon as the thickness of the film was reduced to below a
millionth of a millimetre (or a 25,000,000th part of an inch). The
obvious interpretation, which is confirmed in innumerable ways, is that
olive oil consists of discrete particles—analogous to the “grains” in a
pile of sand—each having a diameter somewhere in the neighbourhood of a
25,000,000th part of an inch.
Every substance consists of such “grains.” They are called molecules,
and the familiar properties of matter are those of layers many
molecules thick; the properties of layers less than a single molecule
thick are known only to the physicist in his laboratory.
MOLECULES
How are we to break up a piece of substance into its ultimate grains,
or molecules? It is easy for the scientist to say that, by subdividing
water for long enough, we shall come to grains which cannot be
subdivided any further; the plain man would like to see it done.
Fortunately the process is one of extreme simplicity. Take a glass of
water, apply gentle heat underneath, and the water begins to evaporate.
What does this mean? It means that the water is being broken up into
its separate ultimate grains or molecules. If the glass of water
could be placed on a sufficiently sensitive spring balance, we should
see that the process of evaporation does not proceed continuously,
layer after layer, but jerkily, molecule by molecule. We should find
the weight of the water changing by jumps, each jump representing
the weight of a single molecule. The glass may contain any integral
number of molecules but never fractional numbers—if the fractions
of a molecule exist, at any rate they do not come into play in the
evaporation of a glass of water.
Public-domain text, read in full here on John Shaqi.
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