At high temperatures the molecules may have even greater speeds; the
molecules of steam in a boiler may move at 1000 yards a second.
It is the high speed of molecular motion that is responsible for the
great pressure exerted by a gas; any surface in contact with the gas
is exposed to a hail of molecules each moving with the speed of a
rifle-bullet. For instance, the piston in a locomotive cylinder is
bombarded by about 14 × 10²⁸ molecules every second. This incessant
fusillade of innumerable tiny bullets urges the piston forward in the
cylinder, and so propels the train. With each breath we take, swarms of
millions of millions of millions of molecules enter our bodies, each
moving at about 500 yards a second, and nothing but their incessant
hammering on the walls of our lungs keeps our chests from collapsing.
Perhaps the best general mental picture we can form of a gas is that of
an incessant hail of shot or rifle-bullets flying indiscriminately in
all directions, and running into one another at frequent intervals. In
ordinary air each molecule collides with some other molecule about 3000
million times every second, and travels an average distance of about
1/160,000 inch between successive collisions. If we compress a gas to
a greater density, more molecules are crowded into a given space, so
that collisions become more frequent and the molecules travel shorter
distances between collisions. If, on the contrary, we reduce the
pressure of the gas, and so lessen its density, collisions become less
frequent and the distance of travel of a molecule between successive
collisions—the “free-path” as it is called—is increased. In the lowest
vacua which are at present obtainable in the laboratory, a molecule
can travel over 100 yards without colliding with any other molecule,
although there are still 600,000 million molecules to the cubic inch.
Under astronomical conditions still lower vacua may occur. In some
nebulae molecules of gas may travel millions of miles without a
collision, so few are the molecules to a given volume of space.
It might be thought that the flying molecules would soon be brought to
rest by their collisions; rifle-bullets undoubtedly would, but not the
molecule bullets of a gas, for reasons now to be explained.
Public-domain text, read in full here on John Shaqi.
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