While it was still engaged in breaking up the atom into its
component factors, physical science was beginning to discover that
the nuclei themselves were neither permanent nor indestructible.
In 1896, Becquerel had found that various substances containing
uranium possessed the remarkable property, as it then appeared,
of spontaneously affecting photographic plates in their vicinity.
This observation led to the discovery of a new property of matter,
namely radio-activity. All the results obtained from the study of
radio-activity in the few following years were co-ordinated in the
hypothesis of “spontaneous disintegration” which Rutherford and Soddy
advanced in 1903. According to this hypothesis in its present form,
radio-activity indicates a spontaneous break-up of the nuclei of the
atoms of radio-active substances. These atoms are so far from being
permanent and indestructible that their very nuclei crumble away with
the mere lapse of time, so that what was once the nucleus of a uranium
atom is transformed, after sufficient time, into the nucleus of a lead
atom.
The process of transformation is not instantaneous; it proceeds
gradually and by distinct stages. During its progress, three types of
product are emitted, which are designated α-rays, β-rays, and γ-rays.
These were originally described as rays because they have the power
of penetrating through a certain thickness of air, metal, or other
substance. Their true nature was discovered later. It is well known
that magnetic forces such as, for instance, occur in the space between
the poles of a magnet, cause a moving particle charged with electricity
to deviate from a straight course; it deviates in one direction or the
other according as it is charged with positive or negative electricity.
On passing the various rays emitted by radio-active substances through
the space between the poles of a powerful magnet, the α-rays were found
to consist of particles charged with positive electricity, and the
β-rays to consist of particles charged with negative electricity. But
the most powerful magnetic forces which could be employed failed to
cause the slightest deviation in the paths of the γ-rays, from which
it was concluded that either the γ-rays were not material particles
at all, or that, if they were, they carried no electric charges. The
former of these alternatives was subsequently proved to be the true one.
α-PARTICLES. The positively charged particles which constitute α-rays
are generally described as α-particles. In 1909 Rutherford and Royds
allowed α-particles to penetrate through a thin glass wall of less than
a hundredth of a millimetre thickness into a chamber from which they
could not escape—a sort of mouse-trap for α-particles. They found that
so long as the number of α-particles in the vessel went on increasing,
an accumulation of helium was forming. In this way it was established
that the positively charged α-particles are simply nuclei of helium
atoms.
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